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Drill:. Ionic bonding Objective: Swbat : Demonstrate sharing of electrons in order to model covalent bonding by combining Lewis dot diagrams. SAT ENRICHMENT:. The bonds in BaO are best described as…. Covalent, because valence electrons are shared.
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Drill: • Ionic bonding • Objective: • Swbat: Demonstrate sharing of electrons in order to model covalent bonding by combining Lewis dot diagrams.
SAT ENRICHMENT: • The bonds in BaO are best described as…. • Covalent, because valence electrons are shared. • Covalent, because valence electrons are transferred. • Ionic, because valence electrons are shared. • Ionic, because valence electrons are transferred. • Metallic, because valence electrons exist in a “mobile sea”.
ENGAGEMENT: • Safari Montage Video: Properties of Compounds: Covalent Bonding: http://10.4.1.240/?p=d9e9fc51-8f49-11df-8b67-002219bf32de
Covalent Bonding WebQuest! • Covalent Bonding Webquest (SR.CHEMBOND.02A) • http://www.visionlearning.com/library/module_viewer.php?mid=55&mcid=&l= 30 min
Covalent Compounds • Covalent Bonds • Two nonmetals • Weaker than ionic bonds • Electrons shared, not transferred
Covalent Compounds • Example: Chlorine and fluorine (ClF) • Problem 1: Sulfur and oxygen (SO) • • • • ◙ ◙ ◙ ◙ • • → • • Cl + F ◙ Cl F ◙ • • ◙ ◙ ◙ ◙ • • • • ◙ ◙ ◙ ◙ • • • • ◙ • • → • • O ◙ S + O ◙ S ◙ • • • ◙ ◙ ◙ ◙ • ◙ ◙ ◙ ◙
Covalent Compounds • Problem 2: Selenium and bromine (SeBr2) • Problem 3: Carbon and oxygen (CO) • • • • • ◙ ◙ ◙ ◙ • • • • → Br Se Br Se Br + + ◙ ◙ ◙ ◙ • • • • • • ◙ ◙ • • • • • • • ◙ ◙ • • Br • • • • • ◙ ◙ • → • C + ◙ O ◙ C ◙ ◙ O ◙ • • • • ◙ ◙ ◙ ◙ • ◙
Bond Polarity If there is an unequal sharing of electrons, the bonding electrons spend more time near the atom with the highest electronegativity causing it to obtain a slightly negative charge. The atom with the lower electronegativity acquires a slightly positive charge.
Electronegativities • Electronegativities for the first six periods • The difference between two elements’ electronegativities indicates the degree of electron sharing (or transfer) in a chemical bond • The closer the electronegativity, the more equally the electrons are shared.
Polar or Nonpolar? Nonpolar Covalent Bond- • Electronegativity difference ≤ 0.4 Polar Covalent Bond • 0.4 < Electronegativity difference < 1.7
Predicting Bond Type Example 1: OF2 • EN of O = 3.5 • EN of F = 4.0 • 4.0 – 3.5 = 0.5 0.5 is less than 1.7 but greater than 0.4, so the bond is polar covalent.
Predicting Bond Type • Example 2: Cl2 • EN of Cl = 3.0 • 3.0 – 3.0 = 0.0 • 0 ≤ 0.4, so the bond is nonpolar covalent.
Predicting Bond Type Example 3: CS2 C: 2.5 S: 2.5 2.5 – 2.5 = 0.0 Nonpolar Covalent
Predicting Bond Type Example 4: NH3 N: 3.0 H: 2.1 3.0 – 2.1 = 0.9 Polar Covalent
Special Case: Polar Covalent • Polar covalent molecules have a dipole • Molecules with dipoles have partially charged ends • For water: • Oxygen has an electronegativity of 3.5 • Hydrogen has an electronegativity of 2.1 • Because oxygen is more electronegative, it will be the negative end of the dipole • Because hydrogen is less electronegative, it will be the positive end of the dipole ◙ ◙ O H ◙ ◙ • Negative ◙ • ◙ H Positive
Bonding • Complete bonding worksheet 10 min
Summary: • Did we accomplish the objective? Explain. • Define a Covalent bond. • What criteria would you use to assess whether a bond is ionic or covalent? • What criteria would you use to assess whether a bond is polar or nonpolar?
Homework: • Chromatography Pre-Lab • (NO HOMEWORK PASSES MAY BE USED)
Drill: • Quiz: Covalent Bonding (5 min) • Objective: • Swbat: Demonstrate sharing of electrons in order to model covalent bonding by combining Lewis dot diagrams.
SAT ENRICHMENT: • Generally… valence electrons are needed for atoms to be most stable. • 2 • 6 • 8 • 18 • 32
Chromatography Lab • Review Lab procedures. • Chromatography Lab 45 min
Exit Ticket & Extension • Covalent Bonding Exit ticket • Extension: Oil and Soap Molecule Simulation: http://intro.bio.umb.edu/111-112/111F98Lect/soapandoil.html 5 min
Summary • Did we accomplish the objective? Explain. • Identify the purpose of the chromatography lab. • Explain your chromatography lab results. Which colors were soluble in water?
Homework • Instructional Fair Pages 38 and 39!