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Molecular Orbitals

Two interacting orbitals make two new orbitals . Using a 1s orbital on two H atoms:. Molecular Orbitals. anitbonding orbital = higher energy. bonding orbital = lower energy. Atomic orbitals on the sides; molecular orbitals inside. MO Diagrams: H and He molecules.

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Molecular Orbitals

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  1. Two interacting orbitals make two new orbitals. Using a 1s orbital on two H atoms: Molecular Orbitals anitbonding orbital = higher energy bonding orbital = lower energy

  2. Atomic orbitals on the sides; molecular orbitals inside. MO Diagrams: H and He molecules

  3. Atomic orbitals on the sides; molecular orbitals inside. MO Diagrams

  4. Two interacting orbitals make two new orbitals. Using a 1s orbital on two H atoms: MOs involving p orbitals sigma orientation = pointing at each other pi orientation = pointing side-by-side

  5. p-Orbital MO Diagrams Li2 – N2

  6. p-Orbital MO Diagrams Li2 – N2 What about the 1s and 2s orbitals?

  7. p-Orbital MO Diagrams Li2 – N2

  8. p-Orbital MO Diagrams O2 – Ne2

  9. p-Orbital MO Diagrams O2 – Ne2

  10. HeteronuclearDiatomics: CO

  11. Photoelectron Spectroscopy Evidence of Molecular Orbitals

  12. http://employees.oneonta.edu/viningwj/sims/molecular_orbital_theory_m.htmlhttp://employees.oneonta.edu/viningwj/sims/molecular_orbital_theory_m.html

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