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Cbz = carbobenzyloxy (removed by hydrogenolysis )

Li, Wenhua ; Gan , Jiangang ; Ma, Dawei . Total synthesis of piperazimycin A: A cytotoxic cyclic hexadepsipeptide . Angewandte Chemie , International Edition (2009), 48(47), 8891-8895, S8891/1-S8891/85. Cbz = carbobenzyloxy (removed by hydrogenolysis ).

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Cbz = carbobenzyloxy (removed by hydrogenolysis )

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  1. Li, Wenhua; Gan, Jiangang; Ma, Dawei. Total synthesis of piperazimycin A: A cytotoxic cyclic hexadepsipeptide. AngewandteChemie, International Edition (2009), 48(47), 8891-8895, S8891/1-S8891/85.

  2. Cbz = carbobenzyloxy (removed by hydrogenolysis) Troc = trichloroethoxycarbonyl (removed by beta-elimination, usually enacted by treatment with zinc)

  3. Appel Reaction

  4. Appel Reaction

  5. FmocOSu =

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