How to Calculate Your Emissions

1. How to Calculate Your Emissions E = A × EF CO PM 2000 lb/ton VOC NOx 2014 Emissions Inventory Workshop

2. General Equation • For most emission sources the following equation is used: • E = A * EF • Where • E = Calculated emissions • A = Activity or annual process rate • EF = Emission factor - determined by the method of calculation • Example sources: • AP-42 • WebFire • Permit 2014 Emissions Inventory Workshop

3. Industrial Boiler – CO Calculation Process: 10-100 mmbtu/hr boiler SCC: 10200602 Fuel: Natural Gas Capacity: 84 mmbtu/hr Control: Uncontrolled 2014 Emissions Inventory Workshop

4. US EPA CHIEF Website: http://www.epa.gov/ttn/chief/index.html 2014 Emissions Inventory Workshop

5. 2014 Emissions Inventory Workshop

6. 2014 Emissions Inventory Workshop

7. 2014 Emissions Inventory Workshop

8. 2014 Emissions Inventory Workshop

9. Industrial Boiler – CO Calculation 2014 Emissions Inventory Workshop

10. EF A E • E = A * EF = ??? tons Convert to tons: 2014 Emissions Inventory Workshop

11. Industrial Boiler – CO Calculation 2014 Emissions Inventory Workshop

12. Engine – Formaldehyde Calculation Process: 2 - Cycle Lean Burn Natural Gas Engine SCC: 20200252 Fuel: Natural Gas Capacity: 1100 hp Control: Uncontrolled 2014 Emissions Inventory Workshop

13. US EPA CHIEF Website: http://www.epa.gov/ttn/chief/index.html 2014 Emissions Inventory Workshop

14. 2014 Emissions Inventory Workshop

15. 2014 Emissions Inventory Workshop

16. 2014 Emissions Inventory Workshop

17. 2014 Emissions Inventory Workshop

18. 2014 Emissions Inventory Workshop

19. EF A E • E = A * EF = ??? tons Convert to tons: 2014 Emissions Inventory Workshop

20. Engine – Formaldehyde Calculation 2014 Emissions Inventory Workshop

21. Emergency Generator – NOx Calculation Process: Reciprocating emergency generator SCC: 20200102 Fuel: Diesel Capacity: 400 hp Pollutant: NOx Factor: 604 lbs/1000 gal Control: Uncontrolled Operation: 50 hours Activity: 500 gal Heat Content: 137 mmbtu/1000 gal 2014 Emissions Inventory Workshop

22. EF A • E = A * EF = ??? tons E Convert to tons: 2014 Emissions Inventory Workshop

23. Surface Coating – Xylene/VOC Calculation Process: Surface coating – spray painting SCC: 40200101 Pollutant: Xylene, VOC (non-HAP) Paint: Acrylic Red 2014 Emissions Inventory Workshop

24. 2014 Emissions Inventory Workshop

25. E = A * VOC Content * (Xylene:VOC Ratio) = ??? tons Now, for non-HAP VOC: VOC (non-HAP) = Total VOC ̶ Xylene VOC (non-HAP) = 2014 Emissions Inventory Workshop

26. Natural Gas Production – Pneumatic Devices Process: Pneumatic Controllers: High Bleed SCC: 31000242 Pollutant: VOC Bleed Rate: 32.1 scf/hr whole gas 2014 Emissions Inventory Workshop

27. E = Gas Vented * VOC Content = ??? tons = 1406 Mscf wt. % VOC Gas MW Conversion VOC = Gas Vented 19.25 = 9,284 lb 1406 Mscf VOC = VOC Emissions = 9,284 lb = 4.642 tons VOC 2014 Emissions Inventory Workshop

28. Control Equipment Calculations 2014 Emissions Inventory Workshop

29. Control Efficiency Calculations • Capture Efficiency: • The percentage of air emission that is collected and routed to the control equipment. Most control devices have a 100% capture efficiency. • Control Efficiency: • The percentage of air pollutant that is removed from the air stream by the control device. 2014 Emissions Inventory Workshop

30. Stone Quarry – Primary Crushing Calculation Process: Primary Crushing SCC: 30532001 Pollutant: PM10 Control: Water Spraying 2014 Emissions Inventory Workshop

31. Stone Quarry – Primary Crushing Calculation 2014 Emissions Inventory Workshop

32. EF A E • E = A * EF * (1 – Control Efficiency) = ??? tons Account for control: Convert to tons: 2014 Emissions Inventory Workshop

33. Two Controls – Grain Handling Calculation Process: Grain handling for feed manufacture SCC: 30200801 Activity: 10,000 tons Pollutant: PM 10 Factor: 3 lbs/ton Primary Control: Cyclone Secondary Control: Baghouse 2014 Emissions Inventory Workshop

34. A Complex Situation: Capture Efficiency, Primary Efficiency & Secondary Efficiency 2014 Emissions Inventory Workshop

35. Two Controls – Grain Handling Calculation • Capture Device: Hood • Therefore, the other 10% is emitted directly to the atmosphere • Primary control device: Cyclone • The control equipment removes 80% of PM 10 from the emission stream. • Secondary control device: Baghouse • The control equipment removes 98% of PM 10 from the emission stream. 2014 Emissions Inventory Workshop

36. Total E = Captured E + Uncaptured E = ??? tons Captured E = A * EF * CE * (1 – PE) * (1 – SE) Uncaptured E = A * EF * (1 – CE) 2014 Emissions Inventory Workshop

37. A EF • Captured E = A * EF * CE * (1 – PE) * (1 – SE) Account for capture and controls: CE SE PE 2014 Emissions Inventory Workshop

38. Uncaptured E = E * (1 – CE) Account for all PM 10 emissions: Convert to tons: 2014 Emissions Inventory Workshop

39. 1 Amount to Hopper 5,400 lbs * 0.98 = 5,292 lbs 4 30,000 lbs of PM generated Amount to Hopper 27,000 lbs* 0.80 = 21,600 lbs 6 2 3,000 lbs of PM emitted “not captured” 27,000 lbs– 21,600 lbs = 5,400 lbs to the Baghouse Amount emitted to the atmosphere 5,400 lbs – 5,292 lbs = 108 lbs 108 lbs stack emissions + 3,000 lbs “not captured,” emitted as a fugitive = 3,108 lbs = 1.554 tons 5 7 27,000 lbs of PM “captured” , sent to cyclone 3 2014 Emissions Inventory Workshop

40. Other Examples If you would like to see an example calculation for another industry, process, or control equipment not presented today: Please email aei@deq.ok.gov and we will create an example for you. 2014 Emissions Inventory Workshop

41. ODEQ Emissions Inventory Section Program Manager: Mark Gibbs Mark.Gibbs@deq.ok.gov Emissions Inventory Staff: Cooper Garbe Cooper.Garbe@deq.ok.gov Cody Lathrop Cody.Lathrop@deq.ok.gov Michelle Horn Michelle.Horn@deq.ok.gov Justin Milton Justin.Milton@deq.ok.gov Carrie Schroeder Carrie.Schroeder@deq.ok.gov http://www.deq.state.ok.us/aqdnew/emissions/index.htm 2014 Emissions Inventory Workshop