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Explore various information measures in statistical physics, dynamics in quantum mechanics, power law tails, and equilibrium distributions. Understand the significance of uniqueness, extensivity, additivity, and stability in thermodynamics and statistical physics. Delve into quantum systems and MaxEnt calculations for deeper insights.
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Unique additive information measures – Boltzmann-Gibbs-Shannon, Fisher and beyond Peter Ván BME, Department of Chemical Physics Thermodynamic Research Group Hungary • Introduction – the observation of Jaynes • Weakly nonlocal additive information measures • Dynamics – quantum mechanics • Power law tails • Microcanonical and canonical equilibrium distributions • Conclusions
1 Entropy in local statistical physics (information theoretical, predictive, bayesian) (Jaynes, 1957): The measure of information is unique under general physical conditions. (Shannon, 1948; Rényi, 1963) • Extensivity (density) • Additivity (unique solution)
The importance of being unique: Robustness and stability: link to thermodynamics. • Why thermodynamics? • thermodynamics is not the theory of temperature • thermodynamics is not a generalized energetics • thermodynamics is a theory of STABILITY • (in contemporary nonequilibrium thermodynamics) • The most general well-posedness theorems use explicite thermodynamic methods • (generalizations of Lax idea) • The best numerical FEM programs offer an explicite thermodynamic structure • (balances, etc…) Link to statistical physics: universality (e.g. fluid dynamics)
2 Entropy in weakly nonlocal statistical physics (estimation theoretical, Fisher based) (Fisher, …., Frieden, Plastino, Hall, Reginatto, Garbaczewski, …): • Extensivity • Additivity • Isotropy
(unique solution) Boltzmann-Gibbs-Shannon Fisher There is no estimation theory behind!
What about higher order derivatives? • What is the physics behind the second term? What could be the value of k1? • What is the physics behind the combination of the two terms? Dimension dependence Dynamics - quantum systems Equilibrium distributions with power law tails
Second order weakly nonlocal information measures • Extensivity • Additivity • Isotropy in 3D
(unique solution) Depends on the dimension of the phase space.
3 Quantum systems – the meaning of k1 probability distribution Fisher Boltzmann-Gibbs-Shannon • Mass-scale invariance (particle interpretation)
Why quantum? A Time independent Schrödinger equation B Probability conservation Momentum conservation + Second Law (entropy inequality) Equations of Korteweg fluids with a potential
(Fisher entropy) Schrödinger-Madelung fluid Bernoulli equation Schrödinger equation
Logarithmic and Fisher together? Nonlinear Schrödinger eqaution of Bialynicki-Birula and Mycielski (1976) (additivity is preserved): Stationary equation for the wave function: Existence of non dispersive free solutions – solutions with finite support - Gaussons
4 MaxEnt calculations – the interaction of the two terms (1D ideal gas)
symmetry There is no analitic solution in general There is no partition function formalism Numerical normalization One free parameter: Js
Conclusions • Corrections to equilibrium (?) distributions • Corrections to equations of motion • Unique = universal • Independence of micro details • General principles in background Thermodynamics Statistical physics Information theory?
Concavity properties and stability: Positive definite If k is zero (pure Fisher): positive semidefinite!
One component weakly nonlocal fluid basic state constitutive state constitutive functions Liu procedure (Farkas’s lemma):
reversible pressure Potential form: Euler-Lagrange form Variational origin
(Fisher entropy) Schrödinger-Madelung fluid Bernoulli equation Schrödinger equation
Alternate fluid Korteweg fluids: