ESH

1. ESH RSL ENVIRONMENT SAFETY HEALTH RESTRICTED SUBSTANCE LIST Sittichoke Huckuntod, Health and Safety Manager Environment, Health and Safety LS&CO

2. Chemical Management

3. 830 Spot Lifter • MSDS - Contains Perchloroethylene • Scientific name - Tetrachloroethylene • Suspected Carcinogen • Reacts with oxidizers • Decomposes to Phosgene & HCL in fire • Phosgene??? • Recommended PPE: SCBA, PPSaF

4. Topics to Cover Chemical Identification and Hazards • Chemical Identification • How chemicals enter the body • Health Effects Factory Requirements • Know hazards of the chemical • Label Chemicals • Provide PPE • Storing Chemicals • Segregating Chemical • Disposing of Used Chemicals

5. ESH / RSL Factory Summit 08 MSDS Chemical Information Material Safety Data Sheets • Lists chemicals in the product • Physical and health hazards • How to protect workers from the hazards

6. Chemical Identification • Types of chemical hazards • Physical hazards • Transportation Classification label • Health hazards • Route of Entry into the body • Health effect • NFPA/HMIG Hazard Labels

7. TRANSPORT CLASSIFICATION Chemical Identification – Physical Hazards

8. Chemical Identification – Physical Hazard TRANSPORT CLASSIFICATION

9. TRANSPORT CLASSIFICATION Chemical Identification – Physical Hazard

10. Chemical Identification - Health Inhalation breathing Ingestion swallowing Absorbtion Skin contact

11. Carcinogens - cancer-causing compounds. • Teratogens - compounds that can harm the developing fetus, causing birth defects or death. • Mutagens - cause genetic mutations or changes, can cause birth defects or lead to cancer in the exposed person. • Sensitizers - cause a reaction, base on an individual worker’s susceptibility. Chemical Identification - Health

12. Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

13. Know hazards of your chemicals • MSDSs are available for inspection • MSDS are written in language spoken by workers • Workers are trained, and understand the hazards associated with the chemicals they are working with

14. Know hazards of your chemicals Resources • Chemical Supplier • Chemical Manufacturer • Websites • http://www.osha.gov/web/dep/chemicaldata/#target • http://www.cdc.gov/niosh/npg/search.html

15. Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

16. Labels Factory Requirements • All chemical containers are labeled, including secondary containers. • Applies to solids, liquids, and gases • Chemical class is identified • NFPA hazard class or similar label

17. 4 2 1 0 1 2 3 0 Chemical Identification Common Labels Blue – Health Red – Fire (Flammability) Yellow/Orange – Reactivity (Instability) White – Special Hazards 4 – Extreme Hazard 3 – Severe Hazard 2 – Moderate Hazard 1 – Minor Hazard 0 – Least Severe Hazard

18. Labels • Secondary container labels

19. Labels • Labels with Chemical Classification

20. Labels • NFPA labels

21. Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

22. Personal Protective Equipment (PPE)

23. Personal Protective Equipment Factory Requirements • PPE provided to workers prevents chemicals from entering body (inhalation, absorption, ingestion) • Based on MSDS • Respirator cartridges match the hazard • Workers trained on how to properly use and wear PPE • PPE is in good condition

24. Respirators Full Face cartridge Respirator Powered Air Purifying Respirator Half- Face Cartridge Respirator N95 Filter (Dust Mask)

25. Respirators and Cartridges Multi-Gas Organic Vapor and Chlorine Gas Organic Vapor and Acid Gas Organic Vapor

26. PPE • Absorption through the skin/eyes • Gloves • Safety Glasses/goggles • Long Sleeves • Aprons • Closed Toe Shoes

27. PPE

28. Minimizing Exposure Ingestion • Eating, Drinking, or Smoking is not allowed in Chemical Handling or Storage Areas • Sink is provided so workers can regularly Wash Hands • Gloves

29. Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

30. Chemical Segregation Factory Requirement • All chemicals and chemical waste must be segregated into categories to prevent incompatible mixtures and dangerous chemical reactions

31. Chemical Segregation Compatibility Chart Terminology • KEEP APART – Keep at minimum 3m apart • SEGREGATE – Keep in separate compartments of the same store separated by at least a firewall or in separate building • ISOLATE – Keep in separate building or isolate within a cabinet designed for this purpose

32. Chemical Segregation Segregating solvents from the following chemicals? Chemical Keep Apart Segregate Isolate    Sodium Hypochlorite    Acetic Acid    Propane

33. Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

34. Chemical Storage Factory Requirements • All chemicals and chemical waste must be properly stored to prevent accidental chemical release to the environment • Aisles and Forklift Routes are Clearly Marked to prevent chemical containers from being hit or tipped over.

35. Drum Storage Closure device up STACKED less than 4 high CHOCKED to prevent rolling

36. Secondary Containment For a Single Tank • Chemicals must have Secondary Containment to prevent an accidental release or spill kits with materials for containment and absorption • Secondary containment must be 110% of the largest volume container 200 liters 110% or 220 liters

37. Secondary Containment For Multiple Tanks in Single Containment 100 liters 200 liters 110% (200) or 220 liters

38. Chemical Spills Factory Requirements • Chemical spills are cleaned only by trained personnel. • Person assigned to do the clean-up is trained to assess the size of the spill, physical hazards of the material, the health hazards of the spilled material, and how to use the spill containment kit

39. Chemical Spills Factory Requirements: • Proper PPE is provided for clean up • Materials used to clean up the spill are properly disposed

40. Good or Bad Secondary Containment?

41. Storage Area Must Have Safety shower/eye wash Chemical Storage

42. Signs • Storage Area Must Have Signs informing workers of required PPE

43. Fire Extinguisher • Storage Area Must Have a working fire hose or Fire Extinguisher in the chemical storage area

44. Chemical Waste Storage • Chemical waste must be labeled • Chemical waste containers must be inspected weekly for signs of leaks, corrosion, or deterioration.

45. Factory Requirements • Know hazards of your chemicals (Physical and Health) • Labels • PPE • Chemical Segregation • Chemical Storage • Disposal

46. Waste Disposal • Factories must use licensed and approved waste transporters • Waste must be disposed at a licensed & permitted disposal facility.

47. Not in compliance!!!

48. Summary Chemical Identification and Hazards • Chemical Identification • How chemicals enter the body • Health Effects Factory Requirements • Know hazards of the chemical • Label Chemicals • Provide PPE • Storing Chemicals • Segregating Chemical • Disposing of Used Chemicals

49. Questions?