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ELECTROLYSIS. Decomposition using an electric current. Electrolysis Cell. Battery – provides power to start reaction Wires – carry the current Electrodes – carry the electric current into the electrolyte, does not react Cathode – negative electrode, attracts positive ions
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ELECTROLYSIS Decomposition using an electric current
Electrolysis Cell • Battery – provides power to start reaction • Wires – carry the current • Electrodes – carry the electric current into the electrolyte, does not react • Cathode – negative electrode, attracts positive ions • Anode – positive electrode, attracts negative ions • Electrolyte – molten ionic salt, is decomposed by the current
Electrolysis of molten lead bromide http://www.gcsescience.com
Electrolysis of molten lead bromide • Lead bromide = lead + bromine • Fume cupboard – toxic bromine fumes • Carbon electrodes • Heated to melt salt – allows ions to move • Silver beads of lead formed at the cathode (-) • Orange fumes of bromine form at the anode (+)
Extraction of aluminium • Aluminium oxide = aluminium + oxygen • Cryolite is added to reduce the melting point of aluminium oxide • Carbon electrodes are used • Aluminium metal is formed at the cathode • Oxygen gas is formed at the anode • Oxygen reacts with the carbon anode wearing it away, the anode has to be replaced
Purification of Copper • Impure copper is placed on the anode (+) • Pure copper is placed on the cathode (-) • Copper sulphate solution is the electrolyte • No colour change occurs in the electrolyte