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Molecules of Life. Chapter 2 & 3. Water properties. Unique properties based on its structure Oxygen is more electronegative than hydrogen Electrons spend more time with oxygen than with hydrogen Polar covalent bond ie unequal sharing. Water Properties.
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Molecules of Life Chapter 2 & 3
Water properties • Unique properties based on its structure • Oxygen is more electronegative than hydrogen • Electrons spend more time with oxygen than with hydrogen • Polar covalent bond • ie unequal sharing
Water Properties • Unique properties based on its polarity • Oxygen more electronegative than hydrogen results in unequal sharing of electron Slight polar ends
Polarity of Water causes “stickiness” Water molecules “stick” to each other in distinct patterns resulting in organization of molecules
Why is polarity important? • Polarity causes molecules to interact in unique ways that influence life • Encourages formation of hydrogen bonds
Water molecules tendency to “stick” to each other Forms hydrogen bonds in 3-d Results in surface tension Cohesion Why is surface tension important…
Surface Tension in Biology “Jesus Lizard” http://www.visionlearning.com/library/module_viewer.php?mid=57 http://www.youtube.com/watch?v=WpXHpXKZtws
Surfactants • Molecules that disrupt cohesion amongst water molecules
Surfactants Don’t wash your car in the creek or dump soap down the storm wash!
Water molecules tendency to “stick” to other polar molecules Adhesion
Cohesion & Adhesion Adhesion Cohesion
Terminology • Heat= amount of energy associated with the movement of atoms and molecules in matter • Temperature= measures the intensity of heat • 1 calorie is the amount of energy to raise 1 gram of water 1 degree Celcius
High Specific Heat • H bonds retard motion at atomic level • Resists heating • Water has a high heat capacity • Stabilize temperatures • Keeps your body temperature stabilized • Keeps environmental temperature stabilized
High Heat of Vaporization • Relatively large amount of Energy removed when changing water from liquid to gas form • ~600 calories • Lots of Energy required to break H bonds • Important in an organisms ability to moderate its temperature • Evaporative cooling
Evaporative Cooling • Aids in homeostasis maintenance
Physical Properties of Water • Density • Density increases as temp decreases • Water max density 4 degrees C • Molecules move apart Ice floats! water steam ice
Solvent Properties • Solvent properties • Protects ions from one another • Charged substances dissolve • Universal solvent
Interactions with Water • Hydrophillic • Polar or charged • Hydrophobic • nonpolar
Summary of Water’s Properties • Cohesion & Adhesion • Capillary action • Interaction of cohesion & adhesion in small spaces • Moderation of temperature • High specific heat • High heat of vaporization • Density properties • Solvent properties • Hydrophillic vs hydrophobic
Molecule Structure • Monomers • Polymers • Macromolecules
Molecule Formation • Dehydration synthesis • Connection of monomers through covalent bond that yields water • Hydrolysis • Disassembly of polymer into component monomers with the use of water molecule to break covalent bonds
Organic Molecules • Why is carbon so important? • Large, complex, diverse molecules • Abundance of carbon based molecules
Carbon • Reactive • Covalent bonds • Carbon branches (backbones)
Carbon Molecules have Complex Shapes In Biology Shape Maters!!
Carbon Based Molecules • Hydrocarbons • Carbohydrates • Lipids • Proteins • Nucleic Acids
Hydrocarbons • Simplest compounds • Only 2 elements • Carbon • Hydrogen • Different numbers of each element • Ex. Methane CH4 • Unique shape • Shape matters • Physiological importance • Energy rich • Communication • http://www.youtube.com/watch?v=SqGPvxzz50Q
Silverfish and Army Ant • Silverfish use hydrocarbons to mask scent • Access to shelter & food • http://www.sciencedaily.com/releases/2011/11/111130202559.htm
What happens when we add different types of elements to hydrocarbons?
Functional Groups • Groups of atoms that participate in chemical reactions • Influence nature of molecule • Characteristic of carbon molecule types
Carbohydrate Characteristics • Sugar molecules • Energy sources • Hydrophyllic • Structure • 1:2:1 ratio CH2O • Monomers or polymers • Monosaccharides • Disaccharides • Polysaccharides Monosaccharides are rings in aqueous solutions
Monosaccharides • Simple sugars • Basic building blocks for organic molecules • Primary cellular energy • CH2O • Ex. Glucose & fructose C6H12O6
Disaccharides • 2 monosaccharides • Formed via dehydration synthesis
Polysaccharides • Aka complex carbohydrates • Hydrophyllic • Polymers of monosaccharides (3+) • Examples • Starch • Glycogen • Cellulose
Lipids • Most with no polar regions= hydrophobic (insoluble) • Triglycerides • Fats, waxes, oils • Glycerol & 3 fatty acids • Phospholipids • Steroids 3 fatty acids
Insulation • Reduces heat loss
Dietary Fats • Excellent energy source • 2X E of Carbs or proteins • Fat • solid at room temperature • Oils • liquid at room temperature • Hydrogenation= solid • Flavor foods • Slow digestion
Types of Fats • Saturated fats • H atoms at all sites • Ex. Lard, butter, solid fats
Types of fats • Unsaturated fats • Lacking one H atom • Ex. Olive oil, nuts, avocado
Health Implications • Saturated fats • Animal fats • Max # of H atoms ie no double bonds= parallel arrays • Unsaturated fats • Veggie oils • 1+ double bonds = kinks
Waxes • Minimizes evaporation • Protection • Coat leaves, fruits, skin, feathers, fur, ears • 1 fatty acid connected with alcohol • +++++ hydrophobic
Phospholipid Membrane • Provides structure for cell membrane
Steroid Hormones • Hydrophobic • Cholesterol fundamental unit • Cell membranes • Sex hormones
Small difference amongst molecules can result in big differences Testosterone Estrodiol
Protein • Polymers of Amino acid • Complex 3D structure