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Introduction to Fibers II. Measuring Properties – Moisture Terms. hydrophilic (Gr.: hydros = water + philos = love)-fibers with an affinity to water hydrophobic (Gr.: hydros = water + phobos = loathe)-fibers with no affinity to water
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Measuring Properties – Moisture Terms • hydrophilic (Gr.: hydros = water + philos = love)-fibers with an affinity to water • hydrophobic (Gr.: hydros = water +phobos = loathe)-fibers with no affinity to water • The moisture properties of a fiber is determined, in large measure, by its chemical composition; does it have an affinity for water. • Also hydrophilic fibers may either absorb or adsorb water. • Absorb – moisture penetrates into the fiber • Adsorb – moisture bound on the fiber’s surface
Regain = (W – w)/w x 100% Regain & Moisture Content Moisture Content = (W – w)/W x 100%
Mechanical Properties - Tenacity tenacity = strength/λ
Mechanical Properties - Elongation elongation = “stretched length” – original length strain = elongation/original length Often these are multiplied by 100% to give percent elongation and percent strain
Measurement of Mechanical Properties • Initial modulus (stiffness) – resistance to deformation • Ultimate tenacity and strain • Specific work of rupture – energy (stored or released) at time of rupture 2 3 1
Cotton • Seed hair fiber • Hydrophilic – affinity between the hydroxyl groups (OH-) and water (H—OH) • Adsorbs
Wool • 18 different amino acids all with the structure shown to the right General amino acid
Wool • Depending upon the source, wool fibers range in length from 38-375 mm • round, and have a diameter of about 25 µm. • The fibers can be identified by the scales on the surface • Felting
Wool • 2 types of cortical cells • Natural waviness • Because each amino acid has different properties • Hydrophilic • absorbs • Amphoteric – behaves like both acid and base
Silk • Protein fiber • The secretion of the larva of the Bombyx mori moth, used to form its cocoon • The major fiber protein is fibroin, which is composed of 15 amino acids in a polypeptide chain • Very few cystine cross-links • Not amphoteric.
Silk • The larva secretes two 'D' shaped filaments (called brins) simultaneously, held together by the protein gum sericin. • The fibers are highly regular and very lustrous. • The cocoon of the silkworm contains about 800-1200 meters of fiber (two strands); each fiber is about 10 µm thick sericin fibroin
Asbestos • Asbestos is the only naturally occurring mineral fiber • There are 6 forms of asbestos: Six minerals are defined as "asbestos" including, chrysotile, amosite, crocidolite, tremolite, anthophyllite and actinolite • Vast majority of textile fibers are chrysotile asbestos, hydrated magnesium silicate, [Mg3Si2O5(OH)4] • Flame resistant chrysotile
Next • Monday: Short reports • Tuesday: Manufactured Fibers