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Abbrev. Intermediates. II. 7,8-dihydroneopterin triphosphate. II ´. 7,8-dihydromonapterin triphosphate. IIa. 7,8-dihydroneopterin monophosphate. III. folic acid. IV. tetrahydrofolate monoglutamate ± C 1 substituents. V. 7,8-dihydroneopterin (V ox = neopterin). V ´.

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Abbrev

Intermediates

II

7,8-dihydroneopterin triphosphate

II´

7,8-dihydromonapterin triphosphate

IIa

7,8-dihydroneopterin monophosphate

III

folic acid

IV

tetrahydrofolate monoglutamate ± C1 substituents

V

7,8-dihydroneopterin (Vox = neopterin)

7,8-dihydromonapterin (V´ox = monapterin)

VI

6-hydroxymethyl-7,8-dihydropterin

VII

6-hydroxymethyl-7,8-dihydropterin pyrophosphate

VIII

dihydropteroate

IX

dihydrofolate

X

tetrahydrofolate

XI

tetrahydrofolate polyglutamates

XII

chorismate

XIII

4-amino-4-deoxychorismate

XIV

p-aminobenzoic acid

III

Outside

III

GTP

NADPH

DHFR

II´

Glycolaldehyde

L-Glu,

ATP

ADP,

Pi

PPi

folQ

folP

H20

ATP

AMP

folC

folB

folX

folB

NADP

DHNTPase

VII

VI

VIII

IX

II

IIa

V

GCHY-I

NP

DHNA

HPPK

DHPS

DHFS

NADPH

folK

folE

NADP

DHFR

folA

Formate

PPi

Pi

XIV

PTR1

PTR1

PTR1

Pyruvate

NADP

X

NADPH

ADC Lyase

pabAc

ATP +

Glu

Vox

V´ox

VIox

FPGS

folC

XIII

ADP +

Pi

Glu

XI

pabAab

ADC Synthase

Gln

XII

One carbon metabolism

IV

Shikimate pathway

XIV

IV

Pterin branch and de novo

pABA branch

Intact folate salvage

Pterin salvage

pABA salvage

THF-monoglutamate salvage