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This chapter delves into the chemistry of solutions, exploring critical concepts such as the solution process, factors affecting solubility, and various ways to express concentration. It also examines the fascinating world of colligative properties, including real-world examples like the softness of 24K gold compared to 10K or 18K gold, and the reasons behind the addition of helium to scuba tanks. Furthermore, it highlights the importance of knowing solubility rules and touches on the concepts of spontaneity and entropy within solution formation.
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Chapter 13 Solution Chemistry
Overview • 13.1 Solution Process • 13.2 Saturated Solutions • 13.3 Factors Affecting Solubility • 13.4 Ways of Expressing Concentration • 13.5 Colligative Properties
Question • Why is 24K gold softer and more yellow than 10K or 18K? • Red gold Cu/Au • White gold Ni/Au • Why can’t planes be made with Mg metal?
Other solutions • Do fillings ‘leak’? • Solution of Hg, Ag, Zn • Why add He to scuba tanks? • Decrease partial pressure of N2
The Solution Process • Definitions: • Solution • Air • 10 K gold • Pop
The Solution Process • Definitions • Solvent • Solute
The Solution Process • Definitions • Miscible • Suspension
The Solution Process • Definitions • Solvation • Hydration
Gas in gas Gas in liquid Gas in solid Liquid in gas Liquid in liquid Liquid in solid Solid in gas Solid in liquid Solid in solid Nine Solutions
Solubility I • Saturated solution
Solubility II • Unsaturated
Solubility III • Supersaturated • You need to know the solubility rules!
Spontaneity Solution formation Disorder
Entropy • It’s not what it used to be
Question • What does nature favor? • Order or disorder?