Total Synthesis of Panaginsene with Structural Revision. Sujeong Geum and Hee-Yoon Lee . Org. Lett., 2014 , 16 (7), xxxx. Ailun Ma 2014. 5. 16. Introduction. Isolation I solated from the roots of Panax ginseng C.A.Meyer , traditional medicine, important and high-grade health product .
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SujeongGeumandHee-YoonLee. Org. Lett., 2014, 16 (7), xxxx
2014. 5. 16
Isolated from the rootsof Panaxginseng C.A.Meyer, traditional medicine, important and high-grade health product.
Health care effect
Total Synthesis of 1
1 They haveachievedthe ﬁrsttotalsynthesisoftheproposedstructureofpanaginsene 1 andtheactualstructureofpanaginsene 1′ throughtheintramolecularTMMdiyl-mediatedtandemcycloadditionreactionwithhigheficiencyandstereoselectivity.
2 Throughthetotalsynthesis, they conﬁrmedthattheoriginallyassignedstructure 1 mustberevisedtothecorrectstructure 1′.