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Green Chemistry Module for Environmental Chemistry

Topic: Sea-nine Antifoulant . A Marine Pesticide. Chemical Pesticides. InsecticidesHerbicidesDisinfectantsRodenticidesAlgicides. MolluscicidesPisicidesFungicidesAvicides. Foulants . Soft Foulants (algae and seweed)Hard Foulants (barnacles and diatoms). $ Costs of Fouling. Increased fuel

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Green Chemistry Module for Environmental Chemistry

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    1. Green Chemistry Module for Environmental Chemistry A Project with Major Support from the Camille and Henry Dreyfus Foundation Special Grant Program in the Chemical Sciences Additional support was provided by the ACS, the University of Scranton Faculty Development Fund and the Chemistry Department

    2. Topic: Sea-nine Antifoulant A Marine Pesticide

    3. Chemical Pesticides Insecticides Herbicides Disinfectants Rodenticides Algicides Molluscicides Pisicides Fungicides Avicides

    4. Foulants Soft Foulants (algae and seweed) Hard Foulants (barnacles and diatoms)

    5. $ Costs of Fouling Increased fuel consumption, $3 billion/year Increased time in Dry-dock, $2.7 billion/year $ To clean ship $ For being out of service

    6. Environmental Costs of Fouling Increased consumption of fossil fuels (a nonrenewable resource) Increased formation of carbon dioxide (a greenhouse gas) Increased formation of other atmospheric pollutants (nitrogen oxides, sulfur oxides, unburned hydrocarbons, ozone etc.)

    7. Antifoulants Used to control the growth of marine organisms (algae and seaweed-soft foulants; barnacles and diatoms-hard foulants) Usually mixed with the paint as it is applied to the hull Slowly leach form the surface of the hull

    8. Organotin Antifoulants Tributyltin Oxide TBTO

    9. Environmental Concerns of TBTO Half-life of TBTO in seawater is > 6 months Bioconcentration, 104 Chronic Toxicity Thickness of oyster shells Sex changes in whelks Imposex in snails Immune system in dolphins and others?

    10. Ban on Organotin Antifoulants US -Organotin Antifouling Paint Control Act of 1998 (OAPCA) Ban by Japan International Maritime Organization (IMO) complete ban on 1/1/03

    11. Environmentally Preferable Antifoulants Ideal Properties Rapid degradation Nonhazardous environmental concentrations Limited bioavailability Toxic only to target organisms Minimum Bioconcentration

    12. Sea-Nine 211 Antifoulant Rohm and Haas Presidential Green Chemistry Challenge Award Active ingredient 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one (DCOI) Mode of action

    13. Environmental Risk ER= f(toxicity and exposure) DCOI limits ER by limiting exposure

    14. Properties of DCOI Acutely toxic to a wide range of marine organisms (effective anitfoulant) Rapid biodegradation to nontoxic products ( life < 1hour) Low Bioconcnetration (bioconcentration =13) Environmental Conc. < Acute Toxicity level No Chronic Toxicity Rapid partitioning to the sediment (low bioavailability)

    15. Biodegradation of DCOI

    16. Risk Quotient RQ = PEC/PNEC DCOI RQ = 0.024-0.36 TBTO RQ = 15-430 PEC (predicted environmental concentration) PNEC (predicted no-effect environmental concentration)

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