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Solubility Review. 1. Solubility is a measure of the maximum amount of solid that will dissolve in a volume of water. Units: g/L mol/L g/100mL Or even: mL/L for CO 2(g) in water Ksp Solubility Product Saturated solutions No Units Only Changes with Temperature No ICE!

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Solubility review

Solubility

Review


Solubility review

1. Solubility is a measure of the maximum amount of solid that will dissolve in a volume of water.

Units: g/Lmol/Lg/100mL

Or even: mL/L for CO2(g) in water

Ksp

Solubility Product

Saturated solutions

No Units

Only Changes with Temperature

No ICE!

Step #1 Write a dissociation equation for the low solubility salt


Solubility review

2. The solubility (s) of BaCO3 is 5.1 x 10-5 M @ 250 C. Calculate the solubility product or Ksp.

Dissociation net ionic BaCO3(s)⇌ Ba2+ + CO32-

s s s

Ksp = [Ba2+][CO32-]

Ksp = s2

Ksp = (5.1 x 10-5)2

Ksp = 2.6 x 10-9

Adding BaCO3does notincrease [Ba2+] or [CO32-] but it does increase the rate of dissolving and crystallization.

Formation Net Ionic: Ba2+ + CO32- BaCO3(s)

Ba2+

CO32-

BaCO3(s)


Solubility review

2. The solubility (s) of BaCO3 is 5.1 x 10-5 M @ 250 C. Calculate the solubility product or Ksp.

BaCO3(s)⇌ Ba2+ + CO32-

s s s

Ksp = [Ba2+][CO32-]

Ksp = s2

Ksp = (5.1 x 10-5)2

Ksp = 2.6 x 10-9

Adding BaCO3does notincrease [Ba2+] or [CO32-] but it does increase the rate of dissolving and crystallization.

Formation Net Ionic:Ba2+ + CO32- BaCO3(s)

Ba2+

CO32-

BaCO3(s)


Solubility review

3. PbCl2(s)⇌ Pb2+ + 2Cl-

Ksp = 4s3


Solubility review

4. 200.0 mL 0.10 M Pb(NO3)2 is mixed with 300.0 mL of 0.20 M NaCl, will a precipitate occur?

PbCl2(s)⇌ Pb2+ + 2Cl-

200 0.10 M 300 0.20 M 500 500

0.040 M 0.12 M

TIP = [Pb2+][Cl-]2

TIP = [0.040][0.12] 2

= 5.8 x 10-4

Ksp = 1.2 x 10-5 TIP > Ksp ppt forms


Solubility review

5. Changing the Solubility of a Salt

E +Ca(OH)2(s)⇄ Ca2+ + 2OH-

Substance Added Effect on Molar Solubility Effect on Ksp

Ca(NO3)2Decrease none

Na2SO4Increase none

NaOHDecrease none

HCl Increase none

NaCl none none

Ca(OH)2none none

Increase Temperature Increase Increase

Decrease TemperatureDecrease Decrease


Solubility review

6. Mg(OH)2 will have the greatest solubility in:

Mg(OH)2(s) ⇌ Mg2+ + 2OH-

A. NaOH OH- lowers solubility

B. Mg(NO3)2 Mg2+ lowers solubility

C. H2O No effect solubility

D. AgNO3Ag+ increases solubility by reacting with OH-


Solubility review

7. Calculate the maximum number of grams BaCl2 that will dissolve in 0.50 L of 0.20 M AgNO3 solution.

AgCl(s)⇄ Ag+ + Cl-

0.20 M

Ksp = [Ag+][Cl-]

1.8 x 10-10 = [0.20][Cl-]

[Cl-] = 9.0 x 10-10 M

BaCl2(s)⇄ Ba2+ + 2Cl-

4.5 x 10-10 M9.0 x 10-10 M

0.50 L x 4.5 x 10-10mole x 208.3 g = 4.7 x 10-8 g

1 L mole


Solubility review

8. Ionic Solutions:NaCl HCl NH4NO3

Molecular Solutions:C12H22O11

9. What is the answer?

A. NaCl

B. CaCl2

C. AgCl

D. AgBr


Solubility review

10. Ionic Solutions: NaCl HCl NH4NO3

Molecular Solutions: C12H22O11

11. What is the answer?

A. NaCl High

B. CaCl2 High

C. AgCl Low 1.8 x 10-12

D. AgBrLow 5.4 x 10-13