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Learn about the concepts of limiting reactants, excess reactants, and percent yield in chemical reactions. Practice problems included to help grasp the calculations involved. Gain a deeper understanding of how to determine the limiting factor and calculate the theoretical and actual yields.
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Definitions • The Limiting Reactant is the reactant that limits the amounts of the other reactants that can combine and the amount of product that can form in a chemical reaction. • The excess reactant is the substance that is not used up in a reaction.
= 1engine + 4 tires 1 car • If you have two engines and seven tires which is your limiting reactant and which is in excess? 4 tires 2 engines 8 tires 1 engine
= Practice problem#1 • SiO2 + 4HF → SiF4 + 2H2O • If 2.0 moles of HF are exposed to 4.5 moles of SiO2, which is the limiting factor? 2 mol HF 1 mole SiO2 0.5 moles SiO2 4 moles HF
Practice problems • N2H4 + 2H2O2→ N2 + 4 H2O a) Which is the limiting reactant in this reaction when .750moles of N2H4 is mixed with .500 mol of H2O2? • How much of the excess reactant, in moles, is left over?
Practice problems • Pg.368 #’s 20-21
Percent Yield • The theoretical yield is the maximum amount of product that can be produced from a given amount of reactant. (The result of a mass-mass problem) • The actual yield is the measured amount of a product obtained from a reaction.
38.8g actual yield = = theoretical yield 53.0g When 36.8 g of C6H6 react with excess Cl2, the actual yield of C6H5Cl is 38.8g. What is the percent yield of C6H5Cl? • C6H6 + Cl2→C6H5Cl + HCl • Do a mass-mass problem to determine your theoretical yield. • Divide your actual yield by your theoretical yield and convert to percent. .732 x100 = 73.2%