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Hydrogen gas is produced from different processes and is available in an impure form. It is especially true when hydrogen gas is produced by hydrocracking, desulphurization, etc. A purification process is needed to create purified hydrogen gas to use hydrogen.
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Hydrogen gas is produced from different processes and is available in an impure form. It is especially true when hydrogen gas is produced by hydrocracking, desulphurization, etc. A purification process is needed to create purified hydrogen gas to use hydrogen. Typical procedures to obtain the gas include opting for – • Chemical synthesis, • Methane steam reforming, • Off-gassing from ethylene plants, • PSA N2 generating system, • Palladium membrane hydrogenpurifiers, • Dense thin-metal purifier, • Deoxygenation purifier, • Electrochemical purifier, etc. Each of these delivers Hydrogen Purification for specific requirements and budgetary requirements. Choosing pressure swing adsorption is important to capitalize on the volatility of the gas and its lack of polarity to purify contaminated gas streams.
Why choosing the right system is important? The hydrogen generation process includes the production of contaminants and side products that may not be useful for the business. It includes compounds like – • Carbon monoxide • Carbon dioxide • Nitrogen • Water • Untreated hydrocarbons, etc. These methods take advantage of the preferential adsorption of the components or Oxygen generator systems to eliminate these from the hydrogen stream and yield purified gas. Traditionally, the system relies heavily on Oxygen Analyzer, multiple sieves, etc. The sieves are designed using four phases -
• Adsorption phase • Depressurization phase • Regeneration phase • Repressurization phase The impure stream of hydrogen gas is passed through the bed during the absorption process. Here impurities are selectively adsorbed into the molecular sieves under pressure. After the step is completed, regeneration is accomplished by the depressurization phase. It reduces the affinity of the impurities and allows them to be discarded. Further purification is obtained by purging pure hydrogen gas and removing the remaining contaminants. It helps to allow continuous hydrogen generation.
Technology considerations for hydrogen generation system Hydrogen generation systems provide carrier gas for GC and GC/MS applications. These employ many technologies to offer high purity gas. Often the following methods are used to enhance the outcomes - • Proton Exchange Membrane systems combined with palladium diffusion • Proton Exchange Membrane systems combined with PSA generator • Electrochemical purifier • Palladium membrane electrolyzer, etc.
Features and benefits of choosing PSA generator system • Product hydrogen can flush away waste from the system • The reduced moisture content of just 1ppm • Robust and regeneration technology • No high temperature or associated high currents • A continuous flow of gas with no pressure fluctuations or pulsing effects • Maintenance requirements limited to replacement of de-ionizer • No replacement of desiccant or hazardous caustics • Short and easy start-up and shutdown procedure • Simplicity and reliability of operation • Minimal energy consumption • Low operation cost • Using palladium membrane helps to offer dry hydrogen. Limitations of these systems • Larger cell replacement cost • Hydrogen gas used to regenerate the sieve is vented to the atmosphere
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