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Explore the concept of density and precision in matter measurement, including sample problems and strategies for calculations. Learn about extensive and intensive properties, as well as units of measurement systems. Homework assignments included.
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AP ChemistryPreface and Chapter 1 Matter and Measurement Mrs. Hallman 9/2013
Density • Definition: Mass per unit volume of a substance • Formula: D = m/V ; units: g/mL, g/cm3, kg/L
Sample Problem • Sample Problem A piece of copper has a mass of 57.54 g. It is 9.36 cm long, 7.23 cm wide, and 0.95 mm thick. Calculate density (g/cm3). • Strategy • 1. Get dimensions in common units. m = 57.54 g L = 9.36 cm W = 7.23 cm Thickness (Height) = 0.95 mm = 0.095 cm • 2. Calculate volume in cubic centimeters. V = LxWxH = (9.36 cm)(7.23 cm)(0.095 cm) = • 3. Calculate the density. D = m/V Be sure to check sig figs
Density as a conversion factor Sample Problem: Mercury (Hg) has a density of 13.6 g/cm3. What is the mass of 95 mL of Hg in grams? In pounds? • First, note that 1 cm3 = 1 mL • Strategy 1. Use density as a conversion factor to calculate mass (g) from volume. 2. Convert mass (g) to mass (lb) Need to know conversion factor; 454 g = 1 lb
A last thought on density • Density of water changes with temperature – why?
Extensive & Intensive Properties • Intensive property - is a physical property of matter that does not depend on the system size or the amount of material in the system • Examples: density, color hardness, melting point, boiling point • Extensive property – any property that depends on the size of the system. A property that changes as the amount of matter changes. • Examples: mass, volume, temperature, energy released/absorbed
Classification of Matter • State of matter: gas, liquid, solid • Kinetic Molecular Theory: A theory of the behavior of matter at the molecular level • Kinetic Energy: The energy of a moving object, dependent on its mass and velocity • K.E. = 1/2mv2
Matter at the Macroscopic and Particulate Levels • Matter has both • Macroscopic –measurable and observable to the naked eye • Macroscopic properties - color, length • Submicroscopic or particulate –not measurable with a microscope • Particle size, chemical bond length
Matter Q’s • 3 examples • 2 forms of energy • Is energy a form of matter • Symbolic level
Units of Measurement • Measurement System – in summer work • Length base unit – meter • Conversions: 2.54 cm = 1 inch • Mass base unit – kilogram • Conversions: 453.5 g = 1 pound (only on earth!) • Time base unit – second • Conversions: 1 hour = 60 minutes; • 1 minute= 60 seconds (NOTE THESE ARE EXACT NUMBERS)
Derived units • We did this - you tell me! • Volume –
Dimensional Analysis -1 • A problem solving method – • Example: how many seconds in a day ?? • 1 day 24 hours 60 min 60 sec = 1 day 1 hour 1 min
Dimensional Analysis-2 • Find the surface area of a room 20 feet by 12 feet in square meters. ( Use 2.54 cm = 1 inch)
Dimensional Analysis -3 • Using density as a conversion – What is the mass of a gold cube with 2 inch sides? (density of gold =19.3 g/cm3) • Hint: need volume in cubic centimeters -
Accuracy vs. Precision • Accurate – close to the true value • Precision – reproducibility of the measurement • Percent Error:
Problem Solving • State the problem • Organize the information • Determine what you know & what you need to know • Determine the strategy • May stem from prior knowledge • Write down each step • NO WORK NO CREDIT!! • Check your answer • Is it reasonable????
HOMEWORK ASSIGNMENTS • Chapter 1 • Density p. 39 # 21, 23, 25, 55, 57 • Unit Conversions p. 40 31, 33, 35, 37, 53, 59 • Problem solving p. 40 45, 47, 49, 61, 63, 77 • Dimensional Analysis Worksheets • Sig fig review worksheet