Download
1 / 6
60 likes | 156 Views
Learn about gas diffusion, effusion, and deviations from ideal behavior in gases. Find out how molecules mix and escape under pressure, with examples like Nickel and Methane compounds. Understand Van der Waals equation and its importance in nonideal gas theory.
E N D
NH4Cl r1 r2 M2 M1 Gas diffusion is the gradual mixing of molecules of one gas with molecules of another by virtue of their kinetic properties. = NH3 17 g/mol HCl 36 g/mol 5.7
r1 r1 t2 r2 r2 Nickel forms a gaseous compound of the formula Ni(CO)x What is the value of x given that under the same conditions methane (CH4) effuses 3.3 times faster than the compound? t1 M2 M1 2 ) ( x M1 M2 = Gas effusion is the is the process by which gas under pressure escapes from one compartment of a container to another by passing through a small opening. = = r1 = 3.3 x r2 = (3.3)2 x 16 = 174.2 x = 4.1 ~ 4 58.7 + x • 28 = 174.2 M1 = 16 g/mol 5.7
n = = 1.0 PV RT Deviations from Ideal Behavior 1 mole of ideal gas Repulsive Forces PV = nRT Attractive Forces 5.8
Effect of intermolecular forces on the pressure exerted by a gas. 5.8
( ) P + (V – nb) = nRT } } corrected pressure corrected volume an2 V2 Van der Waals equation nonideal gas 5.8
