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The Future (?). Data from past 100 years: CO 2 conc. has risen by 25% average temp. increase: 0.5-0.7 0 C. Current: doubling the CO 2 conc. + 1.8-6.3 0 C (2.5-10.4 0 F by 2100) CO 2 is a major part of the greenhouse effect Earth’s average temperature is increasing.
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The Future (?) Data from past 100 years: CO2 conc. has risen by 25% average temp. increase: 0.5-0.7 0C Current: doubling the CO2 conc. +1.8-6.3 0C (2.5-10.4 0F by 2100) CO2 is a major part of the greenhouse effect Earth’s average temperature is increasing
Shape of Molecules (3.3) Greenhouse gases: CO2, CH4, N2O, O3, H2O, CFCs Not greenhouse gases: O2, N2, Ar Why the difference? Shape!
VSEPR Lewis structures: 2D Reality: 3D • Bonds are made of electrons • Negatively charged • Repel each other (still attracted to protons) • Want to be as far apart as possible!
H H . 109 5 C H H C H H H H Example: Methane CH4: tetrahedral
Fig.3.9 “Trigonal Pyrimidal”
Fig.3.10 “Bent”
Fig.3.11 “Linear”
Fig.03.12 “Bent”
Light and Molecules (3.4) UVB, UVC: Bonds break IR: Can’t break (not enough energy) Can cause vibrations Shape HOW a molecule can vibrate Which wavelength? Bond strength & flexibility, atom masses
What about O2 and N2? • Do not absorb IR radiation • IR does not cause vibration • Can’t “trap” heat • Not greenhouse gases
The Carbon Cycle Sect. 3.5
Fig. 3.17 Where does CO2 come from? Where does it go?
water CaCO3 (limestone) Volcanic vents Respiration/decay Plants & animals Sources of CO2 (natural) CO2
Respiration water Plants H2CO3 Mineral Dep. Pressure/time Fossil Fuels Consumption of CO2 CO2
Fossil Fuel Contribution to Atmospheric CO2: • 6-7 billion tons of carbon released • ~ ½ goes to atmosphere • Since 1860: • CO2 conc. 290 ppm 375 ppm, • Increases ~1.5 ppm/year.
Deforestation • Adds CO2 to air (burning/decay) • Takes away a CO2 remover (trees/plants)
Excess CO2 global warming • Increase in atmos. CO2 is a concern • 3.1-3.5 Gt of carbon/year • How much CO2 is added per year?
Mass # Quantitative Concepts: Mass (3.6) How much does an atom weigh? Depends on the atom Standard: Carbon-12 Atomic #: 6 6p, 6n One Carbon 12 = 12 amu
Atomic # Atomic Mass C 6 Symbol Carbon Name 12.01
What’s with the 12.01??? Carbon: 3 isotopes Carbon-12: 98.89% Carbon-13: 1.11% Carbon-14: ~0.00% Average atomic mass for C = 12.01 amu Atomic mass is an average of all carbon atoms
NO carbon atoms weigh 12.01 amu • Treat ALL carbon atoms as though they weigh 12.01 • 1 Tbs of carbon has about 6.022 x 1023 carbon atoms • 602,200,000,000,000,000,000,000 • Dealing with large numbers of atoms • Average is best