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Physical principles of nanofiber production 6. Electric pressure and liquid body disintegration. D.Lukáš 2010.

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physical principles of nanofiber production 6 electric pressure and liquid body disintegration

Physical principles of nanofiber production6. Electric pressure and liquid body disintegration

D.Lukáš

2010

slide2

Electric pressure is another basic concept in electrospinning besides surface tension and electric bi-layer. Its analysis will start with the derivation of the field strength at the surface of a charged conductive liquid, as given by Smith [35].

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slide3

Two points, Aand B, at the vicinity of the surface of a charged conductive liquid drop.

Field strengths E1 andE2are contributions to the total field strengthE.

E1generated from charges that resides on surface element of drop, denoted by, dS, and

E2 is the field strength contribution of charges from the rest of the liquid and from all other charges in space.

slide4

It is worth to mention that the orientation of the total field strength, E, has to be perpendicular to the surface of the conductor, and the same is presupposed for electrostatic intensities, E1 and E2, since the charge distribution is considered to be in equilibrium.

It is obvious that any tangential component of field strength with respect to the liquid surface should violate the equilibrium since then the charge will move along the liquid surface and the system cannot be considered as a one in equilibrium.

Ehas to be zero in the liquid bulk, otherwise, a charge there should move too. Thus, the induced charge on the liquid drop, causing the field strength value E1, shields the external field inside the drop, as has been shown in the article about the electric bi-layer.

So the analysis may be carried out with the values of field strengths instead of their vector nature.

slide5

Conductive body (liquid body)

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Intensity inside conductive body is zero.

Intensity vectors (on the surface of conductive body) are perpendicular to body surface.

Surface of body is equipotentials.

slide7

As, inside the conductive liquid the total electric field, E(B) strength, is zero, two equations can be constructed for the total field strength at the points A and B. At point B, the following relation holds true.

(3.14)

and at the point A holds

(3.15)

slide8

Due to infinitesimally small distance between points Aand B the absolute values of E1 and E2 at these points may virtually be considered unchanged. On the other hand, since E1 is generated by the surface charge and E2 by the charge in the rest of the liquid sphere and elsewhere in the space, the mutual orientation of these electric intensities varies at points A and B, as has been expressed by equations (3.14) and (3.15). The direct consequence of these Equations is given as:

(3.16)

slide9

Application of Gauss theorem of electrostatics, introduced as Equation (3.4), at the vicinity of the surface element, dS, results in the following relation, as depicted in (Figure 3.3).

(3.17)

slide11

The onset of electrospinning appears under the condition that electric pressure pe exceeds the capillary pressure, pc, i.e. .

This condition for the electrospinning onset will be commonly used further in the text.

slide13

Disintegration of charged liquid conductive bodies to nano-scale matter can be illustrated through a single droplet. The related experimental physics, directly connected to disintegration of water drop under electric field, originated through Zeleny’s [10], Doyle et al. [36] and Berg and George [37] works.

The stability analysis of charged liquid bodies, as carried out by Rayleigh [15], will be presented here in a simplified version to show the limiting charge, q, for spherical droplet disintegration.

slide14

Suppose now that the charged droplet, embedded in a space without any other external charges, is a perfect sphere with radius r. The liquid sphere has uniform surface charge density, and is considered as conductive. Thus, for the whole sphere, having radiusr, the following relation is obtained directly from Gauss theorem of electrostatics,

Nabytá kapka v nulovém vnějším poli.

Gauss theorem

total net charge on the liquid sphere

(3.20)

slide15

According to the statement at the end of the following article, the spherical droplet dissociates under the condition

capillary pressure

Electric pressure

From the inequality, and from Equation (3.20) follows static disintegration criterion.

(3.21)

slide16

The more advanced theoretical foundations for analyzing the dynamic stability of charged droplets were developed by Rayleigh [15]. Rayleigh has shown in the work that capillary wave instability on the droplet surface is responsible for this phenomenon.

He derived the following condition for the onset of destabilization of a perfectly conductive spherical droplet

(3.22)

(3.21)

slide17

The integer,n, belongs to various vibration modes of the liquid droplet. The zero mode, n=0, corresponds to radial oscillations, that are unacceptable for incompressible fluids. The first mode, n=1, represents the reciprocating translational droplet motion. Hence, the smallest possible mode number is n=2.

slide18

The droplet instability can be observed visually as the ejection of a fine jet of highly dispersed daughter droplets whose charge / mass ratios are higher than for the original droplet, as mentioned in Grigor’ev [38].

Freely charged liquid droplets are, in principle, unstable since they elongate to reach the shape of spheroids with the major and minor axes as a and b, respectively, as was showed by Taylor [16].

As the ratio increases, the critical value of Q decreases since on the highly curved spheroid apexes is the charge density significantly greater then on the surface of original spherical droplet. Thus, electric pressure pe grows in these places more rapidly than the capillary one, pc.

slide19

Macro-particles

Nano-particles

slide20

Consequently, it may be stated that charged spheroids are always unstable and therefore, disintegration proceeds inexorably as has been mentioned earlier in the introductory part of this subsection.

It was found that the instability led to creation of daughter droplets that were approximately ten times smaller than the original one.

Daughter droplets and their offsprings obey the same phenomenon too. Hence such cascade of droplet disintegrations leads finally to nanoparicles, i.e. nanodroplets. Analogous, but a complex self-similar process leads to creation of nanofibres from macroscopic liquid jets in the area of electrospinning.

Equation (3.22) represents qualitative explanation of procedures that lead to creation of still tinier objects, made by charged liquid bodies.Electrospraying!

(3.22)

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