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Learn about electric fields in matter, polarization effects, induced dipole moments, and the behavior of charges within atoms and molecules. Explore concepts such as electric displacement, linear dielectrics, conductors, and insulators. Discover how materials get ionized, polarized, and aligned in external electric fields.
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Electric Fields in Matter • Polarization • Field of a polarized object • Electric displacement • Linear dielectrics
Conductors Matter Insulators/Dielectrics All charges are attached to specific atoms/molecules and can only have a restricted motion WITHIN the atom/molecule.
When a neutral atom is placed in an external electric field (E): … positively charged core (nucleus) is pushed along E; … centre of the negatively charged cloud is pushed in the opposite direction of E; • If E is large enough ► the atom gets pulled apart completely => the atom gets IONIZED
For less extreme fields ► an equilibrium is established ……. the attraction between the nucleus and the electrons AND ……. the repulsion between them caused by E => the atom gets POLARIZED
Induced Dipole Moment: (pointing along E) Atomic Polarizability
a +q +q -q -q d E To calculate : (in a simplified model) The model: an atom consists of a point charge (+q) surrounded by a uniformly charged spherical cloud of charge (-q). At equilibrium, ( produced by the negative charge cloud)
At distance d from centre, (where v is the volume of the atom)
Prob. 4.4: A point charge q is situated a large distance r from a neutral atom of polarizability . Find the force of attraction between them. Force on q:
Alignment of Polar Molecules: Polar molecules: molecules having permanent dipole moment • when put in a uniform external field:
Alignment of Polar Molecules: • when put in a non-uniform external field: +q F+ d -q F-
+q F+ E+ d -q E- F-
For perfect dipole of infinitesimal length, the torque about the centre : the torque about any other point:
Prob. 4.9: A dipole p is a distance r from a point charge q, and oriented so that p makes an angle with the vector r from q to p. (i) What is the force onp? (ii) What is the force onq?
Polarization: When a dielectric material is put in an external field: Induced dipoles (for non-polar constituents) Aligned dipoles (for polar constituents) A lot of tiny dipoles pointing along the direction of the field
Material becomes POLARIZED A measure of this effect is POLARIZATION defined as: P dipole moment per unit volume
rs p The Field of a Polarized Object = sum of the fields produced by infinitesimal dipoles
Dividing the whole object into small elements, the dipole moment in each volume element d’ : Total potential :
Prove it ! Use a product rule :
Defining: Surface Bound Charge Volume Bound Charge
surface charge density b volume charge density b
Field/Potential of a polarized object = Field/Potential produced by a surface bound charge b + Field/Potential produced by a volume bound charge b
Physical Interpretation of Bound Charges …… are not only mathematical entities devised for calculation; but represent perfectly genuine accumulations of charge !
Surface Bound Charge d P A dielectric tube Dipole momentof the small piece: = -q +q A Surface charge density:
P A If the cut is not to P : A’ In general:
Volume Bound Charge + + + _ _ _ _ _ + + _ _ _ _ + + A non-uniform polarization accumulation of bound charge within the volume diverging P pile-up of negative charge +
= Net accumulated charge with a volume Opposite to the amount of charge pushed out of the volume through the surface
z P R Field of a uniformly polarized sphere Choose: z-axis || P P is uniform
Potential of a uniformly polarized sphere: (Prob. 4.12) Potential of a polarized sphere at a field point ( r ): P is uniform P is constant in each volume element
Total dipole moment of the sphere: (potential due to a dipole at the origin)
Uniformly polarized sphere – A physical analysis Without polarization: Two spheres of opposite charge, superimposed and canceling each other With polarization: The centers get separated, with the positive sphere moving slightly upward and the negative sphere slightly downward
+ + + + + + + + + + + + + - d - - - - - - - - At the top a cap of LEFTOVER positive charge and at the bottom a cap of negative charge Bound Surface Charge b
- _ _ d + + + Recall: Pr. 2.18 Two spheres , each of radius R, overlap partially.
+ + + + + + + + + + + + + - d - - - - - - - - Electric field in the region of overlap between the two spheres For an outside point:
Prob. 4.10: A sphere of radius R carries a polarization where k is a constant and r is the vector from the center. (i) Calculate the bound charges b and b. (ii) Find the field inside and outside the sphere.
The Electric Displacement Polarization Accumulation of Bound charges Total field = Field due to bound charges + field due to free charges
Gauss’ Law in the presence of dielectrics Within the dielectric the total charge density: free charge bound charge caused by polarization NOT a result of polarization
Gauss’ Law : Electric Displacement ( D ) :
Boundary Conditions: On normal components: On tangential components:
Linear Dielectrics Recall: Cause of polarization is an Electric field For some material (if E is not TOO strong) Electric susceptibility of the medium Total field due to (bound + free) charges
In a dielectric material, if e is independent of : Location ► Homogeneous ► Linear Magnitude of E ► Isotropic Direction of E
In linear (& isotropic) dielectrics; Permittivity of the material The dimensionless quantity: Relative permittivity or Dielectric constant of the material
Electric Constitutive Relations and / or Represent the behavior of materials