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Synthesis and Properties of Nanocrystalline Diamond. Y. Tzeng Auburn University Alabama, USA (Part of this set of slides were presented by YK Liu for ELEC 7970 instructed by Y. Tzeng in Summer 2003). Why nanocrystalline diamond? .

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synthesis and properties of nanocrystalline diamond

Synthesis and Properties of Nanocrystalline Diamond

Y. Tzeng

Auburn University

Alabama, USA

(Part of this set of slides were presented by YK Liu for ELEC 7970 instructed by Y. Tzeng in Summer 2003)

slide3

Pure nanodiamond is produced by detonation of diamond blend and subsequently by chemical purification.Nanodiamond is a unique product combining:- diamond hardness core chemical inertia- nanosize (4-6 nm)- rounded shape- active surface

Average monocrystal size: 5 nm

Average size of grains: 20-50 nm

Pycnometric density: 3.1-3.2 g/cm3

Specific surface: ~300 m2/g

Bulk weight: 0.4-0.6 g/cm3

Constant of crystal lattice: 0.3573 +/- 0.0005 nm

Beginning of air oxidation: ~450C

Beginning of vacuum graphitization: ~1100C

http://www.nanodiamond.com/4498.html

slide4

Pure rare nanodiamond

(nanometric ultradispersive detonational diamond)

in the form of dry powder.

For small quantities the prices are:

Less than 100 grams                              7 USD for 1 gram

Between 100 grams and 1000 grams    5 USD for 1 gram

Between 1 Kg and 5 Kg                           4.5 USD for 1 gram

http://www.nanodiamond.com/4498.html

carbon phase diagram
Carbon phase diagram
  • Graphite to Diamond Recrystallization catalyzed by metals at High Pressure and High Temperatures
  • Chemical Vapor Deposition (CVD) at lower pressure and temperatures

”Diamond Films And Coatings”, Noyes, 1992.

crystalline carbon
Crystalline carbon

Diamond

sp3 bonded carbon

Graphite

sp2 bonded carbon

Pressure

2.16 A

3.35 A

Temperature

James E. Butler, CVD Diamond Nucleation, Growth, Properties and Applications (ADC/FCT 2001 Short Course)

slide7

Nanodiamond powders synthesis

Shock-induced transformation setup

D.G. Morris, J. Appl. Phys. 51 (4), 1980, p2059

shock induced transformation

Nanodiamond powders synthesis

Shock-induced transformation

D.G. Morris, J. Appl. Phys. 51 (4), 1980, p2059

slide9

Nanodiamond powders synthesis

Diamond in detonation soot

  • The first report on detonation synthesis of powder was by the Russian scientists Pashkov, et al in 1979.
  • TNT mixed with solids composed of C,H,N,O atoms was fired.
  • The explosion yields a product composition mainly of N2,H2O, CO2 and solid carbon, because the equilibrium favors the reaction
  • 2CO→CO2+C (solid) at the very high pressure ~300 kbar
  • The solid carbon is a mixture of different kinds of carbon, micrographite, carbon black, ultradispersed diamond (UDD) etc.
  • The UDD generated with this method has a narrow (typically 5 Å) distribution of particle sizes centered around 50 Å

N.R. Greiner, D.S. Phillips, J.D. Johnson and F. Volk, Nature, p440

nanodiamond powders synthesis

Detonation setup

Nanodiamond powders synthesis

1-case, 3-capsule, 4-mix of 40%RDX and 60%TNT,7-electric detonators

Source: http://web.vru.ru/diamond/opisanie_e.htm

slide11

Nanodiamond powders synthesis

Detonation synthesis

Dry, Wet represents the detonation is in a CO2, water medium, respectively.

K.Iakoubovskii, M.V. Baidakova, B.H. Wouters, A.Stesmans and P.J. Grobet, Diamond and Related Materials 9 (2000), p861

purification of nanodiamond powder

Nanodiamond powders synthesis

Purification of nanodiamond powder
  • Two kinds of liquid phase oxidizing agent to remove the non-diamond
  • carbon and other impurities
  • Step1. Boiled 18% HCl for 1 hour (remove metallic impurities)
  • Step2. Mixture of 6 HClO4 (71%) and 1 HNO3(65%) with stirring for 2 hrs
  • at 200°C
  • Step3. Washed with distilled water
  • Step1. Mixture of 2 H2SO4(98%), 1 fuming H2SO4 (with SO3 content
  • >50%) and 1 HNO3 (65%) boiled at 270°C for 2 hrs
  • Step2. Washed with distilled water

T. Jiang and K.Xu, Carbon Vol.33 No. 12 (1995), p1663

nanodiamond particles

Nanodiamond powders synthesis

Nanodiamond particles
  • Nanodiamond particles
  • Size:
  • spherical particles of 3- 10
  • nm in diameter(TEM)
  • Structure:
  • cubic diamond(electron
  • diffraction pattern)

HR-TEM micrograph of the explosive detonated nanodiamond powders

D.He, L. Shao, W. Gong, E. Xie, K. Xu and G. Chen, Diamond and Related Materials 9 (2000), p1600

nanodiamond particle conductivity

Nanodiamond powders synthesis

Nanodiamond particle conductivity

Sample preparations:

1. Nanodiamond particle slurry

2. Coated on quartz

3. Two electrodes are 1 cm in length and separate a space of 0.5 cm

Results:

1. Conductivity decreases with increasing annealing temp.

2. In the higher temp. range, the samples show a semi-conducting conduction as described by Arrhenius law

J.J. Wang, E.S. Lambers, Solid-State Electronics Vol.42 No.5(1998), 743-747

nanodiamond used in anti friction

in vacuum

in air

Why nanocrystalline diamond?

Nanodiamond used in anti-friction

10um size Al powders were sintered with N.D. particles

HB:98.3

HB:132

Left:Y.Xiang, J.Zhang, C.Jin and Y.Liu, Wear 242 (2000), p202

Right: Q. Ouyang and K. Okada, J. Vac. Sci. Technol. A. 12 (4) 1994, p2577

slide16

http://nano.materials.drexel.edu/NATOARW/NATOPapers/Chapter3/Kuznet.pdfhttp://nano.materials.drexel.edu/NATOARW/NATOPapers/Chapter3/Kuznet.pdf

slide17

Why nanocrystalline diamond?

Nanodiamond used in biology and medicine

The nanocomposite materials, NDC, comprise nanodiamond particles bonded by a graphite-like matrix.

Physical adsorption of ferment

Electric field enhance adsorption

Adsorption (1-4) and desorption (6) of “trypsin” (2.2-2.5 nm) and “glucose oxidase” (5 nm in size, curve 5) for NDC samples.

Adsorption (1-3) and desorption (4) of “trypsin” for a NDC sample in electric field. The intensities are (1) 50, (2) 40, (3,4) 30 V/cm.

Time needed to reach an equilibrium state in other carbon materials, is about 0.5 to 1 hour.

G.U.Ostrovidova, A.V. Makeev, A.V. Biryukov and S.K. Gordeev, Materials science and engineering C 23 (2003),p377

nanodiamond used in biology and medicine

Why nanocrystalline diamond?

Nanodiamond used in biology and medicine

With the presence of active functional groups, adsorption capacity can be much higher. However, the contact with high-energy surface agents lead to a change of conformation and the probability of ferment inactivation is increased.

G.U.Ostrovidova, A.V. Makeev, A.V. Biryukov and S.K. Gordeev, Materials science and engineering C 23 (2003),p377

slide19

Nanodiamond powders synthesis

Field Emission of Nanodiamond particle

Measurement setup:

1. Planar diode configuration with spacing of 100 micrometer

2. The nanodiamond coated on Si was used as the cathode

3. A tungsten wire of 2 mm in diameter was used as anode

Results:

1. A low turn on electric field (emit current reach 1uA) of 3.2 V/um

2. A high current density of ~95 mA/cm2 under applied field 5 V/um

J.J. Wang, E.S. Lambers, Solid-State Electronics Vol.42 No.5(1998), 743-747

slide20

Nanodiamond is unique in the particle size and shape. The diameter of diamond crystals is in the average 5 nanometers. The unique rounded shape offers superior lubricity characteristics with the hardness and wear resistance of diamond.Nanodiamond has many applications and generates improvements in many aspects:- wear resistance, useful life, and mean time between failure- corrosion resistance of steel- angstrom finishes of polished surfaces- physical properties of rubber- strength of PTFE (Teflon-like materials)- lubricating power of oils

http://www.nanodiamond.com/4498.html

slide21

Nanodiamond is cheap. Specific consumption of nanodiamond is on average 0,3-0,5 percent (weight) and 1 mm coating makes up 0,2 grams (1 carat) per 1 square meter.

  • Some applications:
  • Electrochemical and chemical deposition
  • Metal Matrix Composite with aluminium and copper
  • Additive for PTFE (Teflon)
  • Polishing Pastes and Suspensions
  • Additive to rubber
  • Abrasive Tools
  • Lubrificating oils, greases and coolants
  • Systems of Magnetic Recording
  • Intermetallic on the basis of copper, zin and tin
  • Biology and medicine
  • XADC-Armoloy TDC chrome coating
  • CVD Diamond Films
  • Fuel cells electrodes

http://www.nanodiamond.com/4498.html

slide22

Electrochemical Coatings on metal by base metals

or by noble metals:Cr, Ni, Cu, Au, Ag, Zn, Sn, Al, NiB

  • A standard galvanic equipment is used. Add to the coating bath.
  • Intrusion into boundary area of a state of the substance.
  • Average 0,3-0,5 weight %, 1 micron makes up 0,2 g (1 carat) for 1 sq. meter ot about 1 US$ / sq. meter.

Advantages:

  • Reduces order in crystal packing of coating
  • Service life of products is increased 2-10 times
  • Decrease in coating thickness by a factor of 2-3
  • Increase in capacity of galvanic, less time for precipitation with reduction in thickness coating
  • Attractive appearance
  • Reduces release problems during molding
  • Increase in wear-resistance
  • Increase microhardness
  • Sharp fall in friction coefficient
  • Decrease in corrosion resistance and porosity
  • Improvement of adhesion and cohesion
  • Unporositive coating
  • Reduces grain size of coating, savings

http://www.nanodiamond.com/4498.html

slide23

Metal Matrix Composite with Aluminum and Copper

A light metal with mechanical properties close to those of low-grade steel.

  • Mix with metal powder
  • Melt, in vacuum of 1 - 5 torr, or sinterisation
  • Alters crystal structure, changes crystallization process, changing crystal block size. Intrusion into boundary area of a state of the substance.
      • increase in wear resistance
      • increase hardness
      • reduces density

http://www.nanodiamond.com/4498.html

slide24

Additive to PTFE (Teflon)

Intrusion into boundary area of a state of the substance.

  • reduces wear as much as 25 times
  • coefficient of friction as much as 50%
  • stiffness
  • reduction of material added to PTFE

http://www.nanodiamond.com/4498.html

slide25

Polishing Pastes and Suspensions

  • Nanodiamond finishes high precisely materials for radio engineering, electronics, optics, medicine and machine building.
  • Nanodiamond reduces roughness to a few nanometers, or less.
  • Specific consumption of nanodiamond - 1-10 g per 1 sq. m. of processable surface. 1,1 - 1,9 US $ / carat.
  • Intrusion into boundary area of a state of the substance.
  • Perfect unruffled (mirror) surface of any solids, free of defects and dislocations with relief roughness of 2-8 nm
  • Increases hardness

http://www.nanodiamond.com/4498.html

slide26

Additive to Polymers and Rubber

Polymerization from solutions and melts, chemical curing, electron- beam, gas-flame, electrostatic spraying.

1-5 kg per 1000 kg of rubber (polymer) and 1-5 kg per 1000 sq. meters of polymer coating or film. Price is 0,1 - 0,5 US $ for 1 kg of rubber or 0,1 - 0,3 US $ for 1 sq. m. coating at thickness of 1 mm.

  • Resistance to ageing and to abrasive effect
  • Effective stabilizers of thermal ageing of polymers
  • Low friction coefficient of polyfluoroelastomers and perfluoropolymers
  • High friction coefficient of plyisoprenes 
  • Increase breaking temperature 15%
  • Decrease attrition wear 3-5 times
  • Opportunity of replacement of an expensive polymeric raw material by this cheap one
  • Save expensive and deficient components and materials
  • Polymer compositions have a reinforced complex of elastic-strength properties 1,5 -2,5 times.
  • Fluoroelastomers with nanodiamond have the increase in abrasive resistance 2-4 times.
  • Diamond films have dry friction coefficient less than 0,01.
  • Epoxy adhesives on the basis of nanodiamond have high adhesion and cohesion properties.
  • Increases elastic strength and rupture strength by 30%
  • Increase in wear resistance

http://www.nanodiamond.com/4498.html

slide27

Lubricating Oils, Greases, and Lubricant-coolant Liquids

  • Additive to motor and transmission oils, to consistent lubrificants and lubrificant-coolant liquids.
  • Nanodiamond provides high quality sedimentation stable and ecological safe system with size of superhard particles less than 0,5 microns.
  • It's an alternative to expensive oils and special lubrificants.
  • Add 10-200 grams for 1000 kg of oil. Price is up to 125 US $ for 1000 kg of oil or up to 50 US $ for 1000 kg of LCL.
  • Obtain sedimentation stable oils
  • Increase service life of engine
  • Saving in combustible lubrificant materials
  • Increases engine efficiency
  • Decrease friction torque by 20-40%
  • Decrease in wear of rubbed surfaces by 30-40%
  • Fast run-in of pairs of friction

http://www.nanodiamond.com/4498.html

slide28

Abrasive Tools

Compact polycrystalline product by sintering - for polished, grinding and cutting tools

Amplifier of polymeric binder for elastic abrasive tool

In compacts up to 10 US $/g, in polymer matrixes up to 0,5 US $/g.

  • Compact sinters (sintering)
  • Diamond-oxide compositions with oxide of glass-forming type (diamond ceramics).
  • Nanodiamond metallized by clusters of transition metals

http://www.nanodiamond.com/4498.html

slide29

Systems of Magnetic Recording

  • Intrusion into boundary area of a state of the substance.
  • Decreases ferro-magnetic grain
  • Decreases abrasive wear and friction coefficient
  • Increases recording density

http://www.nanodiamond.com/4498.html

slide30

Intermetallic on the Basis of

Copper, Zinc, and Tin

Nanodiamond is an ideal composite material for intermetallics on the basis of copper with zinc or tin for very hard working conditions of friction units when plastic and liquid lubricating materials are displaced.

no more than 15 volume %

Intrusion into boundary area of a state of the substance.

Decreases frictional coefficient 2-6 times

http://www.nanodiamond.com/4498.html

slide31

Biological and Medicine Applications

  • Nanodiamond are super-active sorbents, immobilizers of biologically active substances, they are able to intensify action of medicinal preparations and can be used for oncology, gastroenterology, dermatology and etc. It does not have mutahenious and cancer properties.
  • Nanodiamond applicated as an aqueos and oil suspension at cancer patients.
  • Significant amount of unpaired electrons on nanodiamond surface makes each diamond crystal powerful multicharge radical donor, able to extinguish intensive radical processes, which accompany practically all serous illness of the patient.
  • Individual nanodiamond crystals have the ability to:
  • penetrate through walls of live cells
  • interact with active radicals
  • neutralize pathogenic viruses and bacteria
  • Nanodiamonds have extremely high activity to pathogenic viruses and bacteria, absorbing and destroying them. Nanodiamond is a new generation of antiseptics of specific action.

http://www.nanodiamond.com/4498.html

slide32

Properties and Advantages of Nanodiamond for Biological and Medical Applications

For example, Nanodiamond is applicated as an aqueos and oil suspension for cancer patients.

  • Superactive sorbent
  • Immobilizator of biologically active substances
  • Able to strenghten action of medicinal preparations
  • Normalizes blood pressure
  • Effective at gastric intestinal diseases
  • Effective means for struggle with burns, skin deseases, internal intoxication
  • No mutahenious or cancer properties
  • Untoxic

http://www.nanodiamond.com/4498.html

slide33

Armology Coating for Metals

  • Thickness of coating (0.0001 - 0.0003 inches [2.5 - 7.5 microns] per surface, 1 mm makes up 0,2 g (1 carat) per 1 m2
  • Decreases wear corrosion
  • Decreases friction
  • Increases microhardness and surface hardness (to 92rc plus)
  • Increases abrasion resistance to ceramic-like material
  • Increases adhesion
  • Coating-to-substrate bond - absolute adhesion (will not fracture from substrate, unless substrate fractures or fatigues)
  • Plastic mold life - increased (has shown increase in life of 300 % plus with 30 - 50 % filled materials)

http://www.nanodiamond.com/4498.html

slide34

Other Applications:

CVD Diamond:

Seeding for diamond nucleation

Fuel Cell Electrodes:

Long life and good electrochemical properties.

http://www.nanodiamond.com/4498.html

crystalline carbon35
Crystalline carbon

Diamond

sp3 bonded carbon

Graphite

sp2 bonded carbon

Pressure

2.16 A

3.35 A

Temperature

James E. Butler, CVD Diamond Nucleation, Growth, Properties and Applications (ADC/FCT 2001 Short Course)

slide36

Carbon Onion

HRTEM micrographs of the nanodiamond sample annealed under vacuum at (1) 1170, (2) 1600, (3) 1900, (4) 2140 K. The dark straight contrast lines in (2) correspond to the (111) crystallographic diamond layers. The distance between these lines

is 2.06 A. The dark lines in Figs. (3) and (4) correspond to crystallographic graphite layers. The distance between these lines is 3.5A. The diamond weight fractions (x) of the samples are also presented within each image.

http://nano.materials.drexel.edu/NATOARW/NATOPapers/Chapter3/Kuznet.pdf

slide37

Onion Like Carbon

http://nano.materials.drexel.edu/NATOARW/NATOPapers/Chapter3/Kuznet.pdf

slide38

Nanodiamond film deposition

Nucleation of diamond particles

slide39

http://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdf

slide40

Nanodiamond film deposition

ACTIVATION

Gaseous Processes

e-, heat

H2 2H

CH4 + H CH3 + H2

FLOW AND REACTION

Diffusion

CVD process for diamond film deposition

REACTANTS

Gaseous Reagents

H2 + CH4

Surface Processes

SUBSTRATE

James E. Butler, CVD Diamond Nucleation, Growth, Properties and Applications (ADC/FCT 2001 Short Course)

slide41

http://www.conferences.unimelb.edu.au/icndst-8/Presentations/p2-02-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/p2-02-2.pdf

slide42

http://www.conferences.unimelb.edu.au/icndst-8/Presentations/p2-02-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/p2-02-2.pdf

diamond properties
Diamond Properties

”Diamond Films And Coatings”, Noyes, 1992.

slide44

Diamond properties

High Young’s modulus

Fundamental resonant frequency

Mass sensitivity Sm

(Image after B. Prorok)

(The ratio of diamond and Si3N4 are 5.4 and 2.9)

P.G.Datskos and T.Thundat, Journal of Nanoscience and Nanotechnology 2, 2002, p369

slide45

Diamond properties

High SAW velocity

Fine-pattern lithography or high-speed material are thus the alternatives for obtaining high frequency devices.

Source: http://www.sei.co.jp

nanocrystalline diamond

Why nanocrystalline diamond?

Nanocrystalline diamond

Nanodiamond powders:

  • Nano-scale crystalline
  • Quasi-spherical morphology

Diamond tools

Nanodiamond films:

  • Surface smoothness
  • Optical transparency
  • Electrical conductivity

Diamond membrane (250 nm)

Top and bottom pictures: http://www.CVD-diamond.com ;

middle one: www.conference.unimelb.edu.au/icndst-8 /presentations/6-2.pdf

diamond lens

slide47

Nanodiamond film deposition

Nucleation of diamond particles

http://www.conference.unimelb.edu.au/icndst-8/presentations/6-2.pdf

slide48

Nanodiamond film deposition

Nanocrystalline diamond deposition

  • Replacing the H2 with Ar results in the growth of nanocrystalline diamond
  • Atomic hydrogen plays an important role in suppressing secondary nucleation by regasifying small or nondiamond phase nuclei.
  • The radicals in plasma change from methyl (CH3‧) to dimer (C2)

D. Zhou, D.M. Gruen, L. C. Qin, T. G. McCauley, and A. R. Krauss, J. Appl.

Phys. 84(1998), p1981

slide49

Nanodiamond film deposition

Nanodiamond growth model

D. A. Horner, L. A. Curtiss and D.M. Gruen, Chemical Physics Letters 233 (1995), p243

slide50

Nanodiamond film deposition

Micro- V.S. Nano-crystalline diamond

2%CH4 + 98%H2

1%CH4 +5%H2 + 94% Ar

slide51

Nanodiamond film deposition

Bias-enhanced growth of nanodiamond film

  • MWCVD process
  • 0.5% CH4 in H2
  • negative bias -100V was applied on substrate

.

N. Jiang, K. Sugimoto, K. Nishimura, Y. Shintani and A. Hiraki, J. of Crystal

Growth 242(2002), p362.

slide52

http://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdf

slide53

http://www.conferences.unimelb.edu.au/icndst-8/Presentations/p2-02-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/p2-02-2.pdf

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http://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdf

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http://www.conferences.unimelb.edu.au/icndst-8/Presentations/p2-02-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/p2-02-2.pdf

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http://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdf

slide57

Nanodiamond film deposition

Wear resistance of nanodiamond film

  • Rough diamond: MCD (Ra=0.35 um), Smooth diamond: NCD (Ra=30 nm)
  • Friction coefficient of NCD film is about 0.1 in open air and 0.05 in dry N2.
  • Wear rate of NCD is two orders magnitude lower than MCD.
  • (After polishing of MCD to the same order of surface roughness, very low friction coefficient and wear rate can be achieved )

A.Erdemir, G.R.Fenske, D.M.Gruen and T.McCauley, Surface and Coatings Technology 120-121 (1999) p565.

slide58

Nanodiamond film deposition

Field emission of nanodiamond film

MCD

NCD

  • Due to the non-diamond carbon, NCD shows better field emission properties than MCD.
  • Turn-on fields for S-assisted MCD and NCD film are approximately half of those grown without sulfur.
  • The addition of S enhance the formation of the graphite network and provide some conduction electrons.

S.Gupta, B.R.Weiner and G. Morell, Diamond and Related Materials 11 (2002)p799-803

slide59

http://www.conferences.unimelb.edu.au/icndst-8/Presentations/p2-02-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/p2-02-2.pdf

slide60

Nanodiamond film deposition

SAW propagation on nanodiamond film

Propagation loss is lower as the grain size of diamond is smaller

T.Uemura, S. Fujii, H. Nakahata and T. Imai, IEEE ultrasonic symposium, 2002, p431

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http://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdf

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slide65

http://nanoscience.nrl.navy.mil/files/sekaric_diamond_apl_81_23_2002.pdfhttp://nanoscience.nrl.navy.mil/files/sekaric_diamond_apl_81_23_2002.pdf

http://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdf

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http://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdf

http://nanoscience.nrl.navy.mil/files/sekaric_diamond_apl_81_23_2002.pdf

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http://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdfhttp://www.conferences.unimelb.edu.au/icndst-8/Presentations/6-2.pdf

http://nanoscience.nrl.navy.mil/files/sekaric_diamond_apl_81_23_2002.pdf

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