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MOF overview. MOF recent review issue. http://newsroom.ucla.edu/portal/ucla/srp-view.aspx?id=105680. http://pubs.acs.org/toc/chreay/112/2. Nets derived from the net of the primitive cubic lattice ( pcu ).

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Mof recent review issue
MOF recent review issue

http://newsroom.ucla.edu/portal/ucla/srp-view.aspx?id=105680

http://pubs.acs.org/toc/chreay/112/2


Nets derived from the net of the primitive cubic lattice (pcu).

Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets

Michael O’Keeffe*†‡ and Omar M. Yaghi*‡§

Chem. Rev., 2012, 112 (2), pp 675–702

DOI: 10.1021/cr200205j


SBUs

Figure 5. (a) The Re6Se8(CN)6 unit. (b) The same abstracted as an octahedral SBU.

  • Chem. Rev., 2012, 112 (2), pp 675–702


Linkers
Linkers

  • Chem. Rev., 2012, 112 (2), pp 675–702


Science 18 January 2002: Vol. 295 no. 5554 pp. 469-472 DOI: 10.1126/science.1067208


Intergrown nets
Intergrown nets

Figure 4: Catenation of rings in nets intergrown with their dual structures.

The nets are shown augmented with triangles at the three-coordinated vertices and octahedra at the six-coordinated vertices. a, A pair of identical rings in the self-dual pyr net of MOF-150 (ref. 11). b, A six-membered ring of the qom net (red) of MOF-177 catenated with a ring of the dual net (blue). A pair of three-coordinated vertices are directly linked, as are pairs of six-coordinated vertices.

Nature427, 523-527 (5 February 2004) | doi:10.1038/nature02311; Received 9 September 2003; Accepted 16 December 2003


Microstructures
Microstructures

http://www.mf.mpg.de/de/abteilungen/schuetz/

Figure 14. (a) Top- and (b) cross-sectional view the ZIF-8 membrane synthesized by secondary growth technique. Reproduced with permission from ref 278

Chem. Rev., 2012, 112 (2), pp 933–969


Properties
Properties

Nature Communications 3(604), 2012; DOI: 10.1038/ncomms1618 

Crystal structure of zinc-adeninate MOF. ZN2+, dark blue tetrahedra; C, gray spheres; O, red spheres; N, blue spheres; H, omitted for clarity. I

…exhibits a high surface area (4,300 m2 g−1), one of the lowest crystal densities (0.302 g cm−3) and the largest metal-organic framework pore volume reported to date (4.3 cm3 g−1).


Co2 adsorption
CO2 adsorption

Figure 12. A portion of the crystallographic structure of Ni2(dobdc) following dosing with CO2. Green, gray, and red spheres represent Ni, C, and O atoms, respectively; H atoms are omitted for clarity.(193)

http://www.sigmaaldrich.com/technical-documents/articles/materials-science/metal-organic-frameworks/ni-mof-74.html


Separations
Separations

Table 10. Components of the Shifted Products of Steam Methane Reformation(417)

Chem. Rev., 2012, 112 (2), pp 724–781


Ferroelectric mofs
Ferroelectric MOFs

Figure 9. Structures of [(NH4)Li(C4H4O6)]·H2O in the paraelectric phase (293 K): (a) unit cell along the c axis and (b) layer structure in the ab plane. Green dotted lines represent hydrogen bonds.

Chem. Rev., 2012, 112 (2), pp 1163–1195

Temperature dependence of dielectric constant of (a) [(NH4)Li(C4H4O6)]·H2O


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