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Oxalate ( µ mol / gFW )

Supplementary Data 1 Miyagi et al. New Leaves. r =-0.702**. Isocitrate ( µmol/gFW ). Oxalate ( µ mol / gFW ). r =0.052. Ascorbate ( µmol/gFW ). Citrate ( µmol/gFW ). r =0.195. r =0.389. Itaconate ( µmol/gFW ). Itaconate ( µmol/gFW ). 10 mM Itaconate 1 weeks. 10 mM Itaconate 2 weeks.

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Oxalate ( µ mol / gFW )

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  1. Supplementary Data 1 Miyagi et al. New Leaves r=-0.702** Isocitrate (µmol/gFW) Oxalate (µmol/gFW) r=0.052 Ascorbate (µmol/gFW) Citrate (µmol/gFW) r=0.195 r=0.389 Itaconate (µmol/gFW) Itaconate (µmol/gFW) 10 mM Itaconate 1 weeks 10 mM Itaconate 2 weeks 10 mM Itaconate 3 weeks

  2. Fumarate Fumarate Fumarate Malate Malate Malate Gln Gln Gln G1P G1P G1P Oxalate Oxalate Oxalate 3PGA 3PGA 3PGA PEP PEP PEP 2OG 2OG 2OG His His His Pro Pro Pro Met Met Met Thr Thr Thr Arg Arg Arg Asn Asn Asn Ile Ile Ile Val Val Val Lys Lys Lys Leu Leu Leu Phe Phe Phe Tyr Tyr Tyr GABA GABA GABA Citrulline Citrulline Citrulline Cinnamate Cinnamate Cinnamate Glu Glu Glu R5P R5P R5P Ru5P Ru5P Ru5P G6P G6P G6P DHAP DHAP DHAP Ala Ala Ala Ser Ser Ser Trp Trp Trp Cys Cys Cys Citrate Citrate Citrate Succinate Succinate Succinate Pyruvate Pyruvate Pyruvate Shikimate Shikimate Shikimate Asp Asp Asp FBP FBP FBP Gly Gly Gly Aconitate Aconitate Aconitate 6PG 6PG 6PG Coumarate Coumarate Coumarate RuBP RuBP RuBP Ascorbate Ascorbate Ascorbate Ornithine Ornithine Ornithine Isocitrate Isocitrate Isocitrate Supplementary Data 2 Miyagi et al. Stems a d PC 2 (18.1 %) : Organic acid PC 1 loadings : Amino acid : Phosphorylated compound PC 1 (35.1 %) b e PC 3 (10.4%) PC 2 loadings PC 1 (35.1 %) c f PC 3 (10.4%) PC 3 loadings PC 2 (18.1 %) Control 0 week Control 1 week Control 2 weeks Control 3 weeks 10 mM Itaconate 0 week 10 mM Itaconate 1 weeks 10 mM Itaconate 2 weeks 10 mM Itaconate 3 weeks

  3. Supplementary Data 3 Miyagi et al. Stems r=-0.488* r=-0.113 Isocitrate (µmol/gFW) Oxalate (µmol/gFW) r=-0.396 Citrate (µmol/gFW) Ascorbate (µmol/gFW) r=-0.058 Itaconate (µmol/gFW) Itaconate (µmol/gFW) 10 mM Itaconate 0 week 10 mM Itaconate 1 weeks 10 mM Itaconate 2 weeks 10 mM Itaconate 3 weeks

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