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HO. OH. B. CH 3. CH 3. HO. HO. O. O. HO. OH. OH. CH 3. HO. HO. O. O. O. CH 3. HO. O. HO. HO. O. HO. R -THMF. MHF. S -THMF. OH. CH 3. O. O. -. CH 3. OH. O. O. HO. HO. R -DHMF. S -DHMF. OH. O. Pfs. OH. O. LuxS. DPD. LuxP Ligand. LsrB Ligand. Toxic

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Presentation Transcript

HO

OH

B

CH3

CH3

HO

HO

O

O

HO

OH

OH

CH3

HO

HO

O

O

O

CH3

HO

O

HO

HO

O

HO

R-THMF

MHF

S-THMF

OH

CH3

O

O

-

CH3

OH

O

O

HO

HO

R-DHMF

S-DHMF

OH

O

Pfs

OH

O

LuxS

DPD

LuxP Ligand

LsrB Ligand

Toxic

Metabolite

AI-2

is a

group

of

molecules

-2 H2O

+ B(OH)4-

S-THMF-borate

-H2O

-H2O

H2O

H2O

Fig 2

AI-2 is made

by LuxS

SAH

X-CH3

SRH

X

LuxS

has

metabolic

function

OA

HCY

SAM

MetB

CysK

MET

SO42-

S2-

CYS

protein

Activated Methyl Cycle


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