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PONOP Attributes

PONOP Attributes. Elizabeth Korsmo, Goldberg Lab, University of Washington. Ir(COE) 2 (acetone) 2 ┐ PF 6. Ir(COE) 2 (Cl) 2 + AgPF 6 (in acetone, diethyl ether). PONOP Ligand Synthesis. Heat in oil bath at 40C. Day 6, 31 P NMR ( from R to L )

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PONOP Attributes

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  1. PONOP Attributes Elizabeth Korsmo, Goldberg Lab, University of Washington

  2. Ir(COE)2(acetone)2┐PF6 Ir(COE)2(Cl)2 + AgPF6 (in acetone, diethyl ether)

  3. PONOP Ligand Synthesis Heat in oil bath at 40C Day 6, 31P NMR (from R to L) PONOP, tertb-P-Cl, fragment

  4. (PONOP)Ir(COE) ┐PF6

  5. (PONOP)Ir(H)(Ph)┐PF6

  6. (PONOP)Ir(Ph)

  7. Acknowledgements • Karen Goldberg, UW Chemistry Professor • Sara Buzak, graduate student • The Goldberg Research Group • Center for Enabling New Technologies Through Catalysis (CENTC) • NASA Spacegrant SURP & the Mary Gates Endowment

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