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Structure

Structure / Reactivity Relationships. Organic chemists generally classify the manner in which substituents modify chemical reactivity into three categories:Inductive and Field effects (Polar effects)Resonance effects (Conjugative effects)Steric effects. Structure / Reactivity Relationships. Po

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Structure

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    1. Structure / Reactivity Relationships Basic Premise of Organic Chemistry - The nature of the chemical reaction an organic molecule undergoes is dependent upon the functional groups present in the molecule. Corollary - Structural features in the molecule at sites that are not directly involved in a particular chemical transformation can affect both the kinetics and the equilibrium of the chemical reaction.

    2. Structure / Reactivity Relationships Organic chemists generally classify the manner in which substituents modify chemical reactivity into three categories: Inductive and Field effects (Polar effects) Resonance effects (Conjugative effects) Steric effects

    3. Structure / Reactivity Relationships Polar Effects

    4. Summary of Common Substituents grouped according to their Inductive effect

    5. Examples of Resonance Effects

    6. Summary of Common Substituents grouped according to Resonance and Inductive effects

    7. Examples of Steric Inhibition of Resonance

    8. Special Substituent effect - Hydrogen bonding

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