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Granitic Site in the Czech Republic and Paired-Catchments Possibilities

Granitic Site in the Czech Republic and Paired-Catchments Possibilities. Pavel Kram, Jakub Hruska, Tomas Navratil, Filip Oulehle, Daniela Fottova and Martin Novak Czech Geological Survey, Prague.

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Granitic Site in the Czech Republic and Paired-Catchments Possibilities

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  1. Granitic Site in the Czech Republic and Paired-Catchments Possibilities Pavel Kram,Jakub Hruska, Tomas Navratil, Filip Oulehle, Daniela Fottova and Martin Novak Czech Geological Survey, Prague

  2. GEOMON Network of Fourteen Forest Catchments in Central Europe (Coordinated by Daniela Fottova, Czech Geological Survey, Prague, since 1994) GER POL GER CZE AUT SVK

  3. Lysina ROAD Hydrochemical monitoring: since 1988 Hydrologic monitoring: since 1989 In the GEOMON network (Daniela Fottová et al.): since 1994 In the ICP-IM network (Sirpa Kleemola et al.): since 2002 ROAD Topographic situation 1989

  4. Different stages of surface runoff and water color at 90O V-notch weir of LYS Flood DOC, H+ Baseflow DOC, H+

  5. Throughfall Collectors in Even-Aged Norway Spruce Plantation at LYS Photo: Galina Koptsik, 2005

  6. Shallow Root System at LYS photo Hofmeister 2003, published Hofmeister et al. 2008

  7. 0.5 m2Soil Pit at LYS – Podzol on Leucogranite Technique: Huntington TG, Ryan DF, Hamburg SP (1988) SSSAJ 52: 1162-1167 Photo: Skorepa J(2006)

  8. MAGIC Model Simulation of Annual Mean Base Saturation of Lumped 90 cm of Soil at Lysina Hruska and Kram (2007)

  9. SAFE Model Simulation of Annual Mean Base Saturation of Five Soil Horizons at Lysina L+F H E B C Navratil et al. (2007)

  10. . POL GER CZE AUT SVK

  11. Lithology Gradientin the Czech GEOMON Network and in the American Critical Zone Exploration Network LYS:Leucogranitevs.PLB:Ultramafic Serpentine GEOMON in paired catchment-level observatories Granitevs.Mafic Basalt Brantley et al. 2006, 2008

  12. Leucogranite versus serpentine(Lysinavs.Pluhuv Bor) Mg Acid rock Mg Sandy soil Ultramafic rock Silty soil

  13. CaO MgO Na2O K2O Al2O3 SiO2 Pluhuv Bor-serpentiniteLysina-leucogranite 0.05 0.5 36.10.1 0.02 2.9 0.02 4.4 1.0 14.0 40.7 72.9 Bedrock composition (mass %) original data: serpentinite: Kram et al., 2007, leucogranite: Fiala F. et al., 1961

  14. Soil Base saturation in 1993 Kram et al. (1997)

  15. Mean Acid Neutralizing Capacity of Streamwater (1994-2005) ANC Navratil et al. (2006)

  16. Real Life Pluhuv Bor Black Brook Lysina 3 ueq/l Ni++ 1992-1994 Kram et al., 2000

  17. 21 “mono-rock” “mineral soil“ catchmens of the Slavkov Forest underlain by 5 geochemically contrasting environments (leucogranite/granite/gneiss+mica schist/ amphibolite+neovolcanites/serpentine) studied in 2001-2003 + 2 “organic soil“ catchments studied in 1992-2007 Input digital space data: sateliteimageLANDSAT ETM+ Malenovsky, Kram, Cudlin, 2004

  18. Mean concentrationsof magnesium in stream waters at 11 catchmentson 3 bedrocks leucogranite serpentine amphibolite

  19. V-notch weir for continuous measurements of surface water runoff from the Pluhuv Bor watershed

  20. Conclusions • Quantification of lithologic controls on regolith, mineral soil and organic soil in (2+21) forest catchments (in monolithologic and tree monoculture environment of central Europe) • Selected paired monolithologic catchments include end-members of ecosystem sensitivity to acidification • Comparison of spatial scales of chemical weathering from laboratory microscale, soil profiles to small catchments

  21. More information about the Czech catchments: Hofmeister J, Oulehle F, Kram P, Hruska J (2008) Loss of nutrients caused by litter raking as compared with an effect of acid deposition. Biogeochemistry88: 139-151. Hruska J, Johnson CE, Kram P(1996) The role of organic solutes in the chemistry of acid-impacted bog waters of the western Czech Republic. Water Resources Research32: 2841-2851. Hruska J, Kram P (2003) Modelling of long-term changes of streamwater chemistry in two catchments with contrasting vulnerability to acidification. Hydrology and Earth System Sciences 7: 525-539. Kram P, Hruska J, Wenner BS, Driscoll CT, Johnson CE (1997) The biogeochemistry of basic cations in two forest catchments with contrasting lithology in the Czech Republic. Biogeochemistry37: 173-202. Krám P(2006) Chemical composition of runoff from eleven forested and geochemically contrasting catchments underlain by leucogranite, serpentinite and amphibolite (in Czech, English Abstract). Geoscience Research Reports, Czech Geological Survey, Prague,182-186. Kram P, Oulehle F, Stedra V, Hruska J, Shanley JB, Minocha R, Traister E(2008) Geoecology of a forest watershed underlain by serpentine in Central Europe. Northeastern Naturalist, in review. Navratil T, Kurz D, Kram P, Hofmeister J, Hruska J (2007) Acidification and recovery of soil at a heavily impacted forest catchment (Lysina, Czech Republic) – SAFE modeling and field results. Ecological Modeling205: 464-474. Novak M, Kirchner JW, Fottova D., Prechova E, Jackova I, Kram P, Hruska J (2005) Isotopic evidence for processes of sulfur retention/release in 13 forested catchments spanning a strong pollution gradient (Czech Republic, Central Europe). Global Biogeochemical Cycles 19: Art.No.GB4012, 1-14. Oulehle F, McDowell WH, Aitkenhead-Peterson JA, Kram P, Hruska J, Navratil T, Buzek F, Fottova D (2008) Long-term trends in stream nitrate concentrations and losses across watersheds undergoing recovery from acidification in the Czech Republic. Ecosystems 11: 410-425.

  22. MAGIC Model Simulation of Annual Mean Streamwater Acid Neutralizing Capacity (ANC) at Lysina Hruska and Kram (2007)

  23. MAGIC Model Simulation of Annual Mean Streamwater Sulfate Concentration at LYS and PLB Hruska and Kram (2007)

  24. MAGIC Model Simulation of Annual Mean Soil Base Saturation at LYS and PLB PLB: PLB: decline of base saturation from 95% to 88% LYS Hruska and Kram (2007)

  25. 0.5 m2soil pit at PLB – Eutric Inceptisol Technique: Huntington TG, Ryan DF, Hamburg SP (1988) SSSAJ 52: 1162-1167 Photo July 1993

  26. Zero-tension lysimeters for sampling of soil water at Pluhuv Bor Photo July 1993

  27. metabasics granite leukogranite volcanics gneiss sediments serpentinite mica-schist

  28. Mean concentrationsof the nutrient potassium and potentially toxic nickelin stream waters at 11 catchmentson 3 bedrocks

  29. Mean concentrationsof the nutrient divalent base cationsin stream waters at 11 catchmentson 3 bedrocks

  30. Outline • Location of fourteen catchments • Methods of water and soil sampling and chemical analyses • “Long-term“ monitoring results (deposition, soil, streamwater) • MAGIC and SAFE modeling results (streamwater, soil) • Short Conclusions

  31. Water Sampling at Lysina (LYS)(for example)

  32. Water Analyses at LYS

  33. Selected Soil Analyses at LYS (sampling in 1993, analyzed at Syracuse University)

  34. Selected Soil Analyses (cont.) at LYS

  35. Results of the Mann-Kendall Test* of the Mean Annual Atmospheric Deposition Fluxes to the GEOMON Catchments in 1994-2005 *Libiseller C. (2004) MULTMK/PARTMK – A program for the computation of Multivariate and Partial Mann-Kendall Test. Linkoping University, Sweden. Kram et al. (2006)

  36. Mean Streamwater Export of Nitrate in 1994-2005 vs. Organic Soil C/N Mass Ratio at fourteen GEOMON Catchments Oulehle et al. (2008)

  37. MAGIC Model Simulation of Annual Mean Soil Base Saturation at other GEOMON Catchments Hruska and Kram (2004)

  38. Conclusions • CZ = Critical Zone • CZ = Czech Republic

  39. More information about biogeochemical models • MAGIC Cosby BJ, Hornberger GM, Galloway JN, Wright RF (1985): Time scales of catchment acidification.Environmental Science and Technology 19: 1144-1149. Cosby BJ, Ferrier RC, Jenkins A, Wright RF (2001): Modelling the effects of acid deposition: refinements, adjustments and inclusion of nitrogen dynamics in the MAGIC model. Hydrology and Earth System Sciences 5: 499-517. • SAFE Warfvinge P, Falkengren-Grerup U, Sverdrup H, Andersen B (1993):Modeling long-term supply in acidified forests stands.Environmental Pollution 80: 209-221. Martinson L, Alveteg M, Warfvinge P (2003):Parametrization and evaluation of sulfate adsorption in a dynamic soil chemistry model.Environmental Pollution 124: 119-125.

  40. Results of the Mann-Kendall Test of the Mean Annual Stream Runoff Fluxes from the GEOMON Catchments in 1994-2005 NS: not significant, P>0.05 Oulehle et al. (2008)

  41. Results of the Mann-Kendall Test of the Mean Annual Streamwater Concentration in the GEOMON Catchments in 1994-2005 NS: not significant, P>0.05 Oulehle et al. (2008)

  42. Mean Calcium and Magnesium Concentration in Streamwater (1994-2005) Ca Mg

  43. Very different proportions of Mg fluxes in throughfall at sites with Mg-poor (LYS) and Mg-rich (PLB) substrate in 1992-2002 Lysina Pluhuv Bor

  44. Decline of internal cycling and dry deposion fluxes of base cations in throughfall in 1994-2002. The pattern of internal cycling follows the large increase of throughfall pH. However the wet deposition fluxes remain stable. Dry deposition flux of base cations was larger than the wet deposition flux in the middle of 1990s, but not later. Lysina Pluhuv Bor

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