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呂良賜 博士研究室

呂良賜 博士研究室. Research Interests: Green Technology Novel Dye for Dye-sensitized Solar Cell Synthetic Chemistry Organometallic Chemistry Fuel Cell (PEM membrane); Fluoropolymer Material Science. Vacuum line. Current Research Projects. 1. Novel Dye w/ Fluorous Polytail (Solar Cell)

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呂良賜 博士研究室

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  1. 呂良賜 博士研究室 • Research Interests: • Green Technology • Novel Dye for Dye-sensitized Solar Cell • Synthetic Chemistry • Organometallic Chemistry • Fuel Cell (PEM membrane); Fluoropolymer • Material Science

  2. Vacuum line

  3. Current Research Projects 1. Novel Dye w/ Fluorous Polytail (Solar Cell) 2. Catalysis (Organometallics) 3. Fuel Cells 4. X-Ray Crystal Growing (Catalysts)

  4. Current Research Projects 5. Green Chemistry • Fluorous Biphasic System (FBS) • Aerobic Alcohol Oxidation under FBS • ATRP (Recoverable) 6. Lithium Battery Polymeric Electrolyte

  5. 1. Lithium Battery Electrolyte • See the next chart for the procedure

  6. 2. Liquid Crystal Materials

  7. Novel Fluorous Dye For DSSC • Novel fluorous ponytailed Dye for Solar Cell

  8. CV and UV/VIS Studies of Pt-based DSSC

  9. Fuel Cell (Proton Exchange membrane)

  10. Green Chemistry 1. FBS:Fluorous biphasic system

  11. 2. Aerobic Alcohol Oxidation under FBS biphasic monophasic biphasic

  12. 3. ATRP (Cu recoverable) 聚合反應進行 反應完成

  13. X-Ray [4,4'-bis(C3F7CH2OCH2)-2,2'-bpy] [4,4'-bis(HC4F8CH2OCH2)-2,2'-bpy]

  14. Departmental Seminar on May 18 Host Speaker: Prof. Thrasher

  15. Attending International Meeting in Yokohama, Japan (2007)

  16. Photo with Nobel Prize Winner, Prof. Grubbs

  17. Publication [A. 期刊論文(以北科大發表之英文期刊; >10 papers)] 1. Norman Lu,* His-Chun Hou, Chien-Ting Lin, Yuh-Sheng Wen, and Ling-Kang Liu, “Synthesis, Structure and Electrochemical Property of Novel (2,2′-Bipyridine)-Metal (M = Pt, Pd) Dichloride with 4,4′-Bis(fluorous-ponytail) on Bipyridine” Eur. J. Inorg. Chem. 2009. (to be submitted) (NSC 96-2113-M-027-004-MY2) 2. Y. Akiyama, S. Fujita, X. Meng,Y.-C. Chen, N. Lu,b,* F. Zhaoc and M. Arai a,*, “Carbon Dioxide Pressure Tunable Heterogeneous and Homogeneous Media for Heck and Sonogashira Coupling Reactions Using Fluorinated Palladium Complex Catalysts” J. Organomet. Chem. 2009 (submitted) (NSC 96-2113-M-027-004-MY2) 3. Norman Lu,* and Ling-Kang Liu, J.C. Jiang “The Intramolecular Blue-shifting C-H···F-C Hydrogen Bond in Solid State”, CrystEngComm2009 (submitted) (NSC 96-2113-M-027-004-MY2) 4. Norman Lu,a,* Yi-Chuan Chen,a Wei-Shung Chen, Ter-Lin Chen, Sy-Juen Wu “Copper-free Sonogashira Reaction under Thermomorphic Mode”, 2009, J. Organomet. Chem. (on-line release 2008, 10, 31), 694 (2), 278-284 (NSC 96-2113-M-027-004-MY2)(SCI:2.168, 12/43) 5. Norman Lu,* Tsung-Chi Chen and Ching-Lung Lin, “New Fluorous Bipyridine Ligands for Cu-catalyzed Atom Transfer Radical Polymerization of Methyl Methacrylate in the Thermomorphic Mode” J. of Applied Polymer Science, 2008, 110 (5), 2531-3303; (NSC 96-2113-M-027-004-MY2)(SCI: 1.008, 39/74) 6. Norman Lu,*, Shih-Chieh Chen, Tsung-Chi Chen and Ling-Kang Liu, “Pd-catalyzed Heck Reaction under ThermomorphicMode” Tetrahedron Letters 2008, 49, 371-375; (NSC 96-2113-M-027-004-MY2), (SCI:2.615, 20/56) 7. Norman Lu,* Yan-Chou Lin, "High Fluorine Content Bis(fluoro-ponytailed) Bipyridine Palladium Complexes as Catalyst for Mizoroki-Heck Reactions under Fluorous Biphasic Catalysis Conditions" J. Chin. Chem. Soc. 2008, 55(1), 89-96; (NSC 95-2113-M-027-002), (SCI: 0.643, 91/128) 8. Norman Lu,* Yan-Chou Lin, “Efficient, Recoverable, Copper-catalyzed Aerobic Oxidation of Alcohols under FBS and Thermomorphic Mode” Tetrahedron Lett 2007, 48, 8823-8828; (NSC 95-2113-M-027-002) (96-2113-M-027-004-MY2) (SCI: 2.615, 20/56) 9. Norman Lu,* Jeng-Yung Chen, Chi-Wen Fan, Yan-Chou Lin, Yuh-Sheng Wen, and Ling-Kang Liu; “Synthesis, Structure and Reactivity of Novel Palladiumdichloride-2,2′-bipyridine with 4,4’-Bis(fluorous-ponytail)” Polyhedron 2007,26, 3045-3053; (NSC 93-2113-M-027-005) (SCI:1.756, 10/25) 10. Norman Lu,* Yu-Mei Ho, Chi-Wen Fan, Fu-Ming Wang and Jyh-Tsung Lee,* “A Simple Method for Synthesizing Polymeric Lithium Salts Exhibiting Relatively High Cationic Transference Number for Solid Polymer Electrolytes” Solid State Ionics2007,178, 347-353; (NSC 93-2113-M-027-005) & (NSC 94-2113-M-027-003)(SCI:2.012, 12/61)

  18. (Continued) 11. Norman Lu,* Yan-Chou Lin,Jeng-Yung Chen, Chi-Wen Fan, and Ling-Kang Liu;“New Bis(fluoro-ponytailed) Bipyridine Ligands for Pd-catalyzed Heck Reactions under Fluorous Biphasic Catalysis Condition” Tetrahedron2007, 63, 2019-2023, NSC 94-2113-M-027-003, (SCI:2.869, 14/56) 12. Norman Lu(呂良賜),* Yan-Chou Lin(林原週), Jeng-Yung Chen(陳政湧), Chi-Wen Fan (范己文), Yuh-Sheng Wen(聞昱生), and Ling-Kang Liu(劉陵崗)* “(2,2’-bipyridine)palladium­dichloride Derivatives as Recyclable Catalysts in Heck Reactions” J. Chin. Chem. Soc. 2006, 53, 1517-1521. NSC 94-2113-M-027-003, (SCI: 0.643, 91/128) 13. Norman Lu,* H. P. Sampath Kumar,James L. Fye, Jian Sun Blanks,Joseph S. Thrasher,* Helge Willner,and Heinz Oberhammer” The Initial Synthesis of the Long Sought After Compound Pentafluoronitrosulfane, SF5NO2” Angew. Chem. Int. Ed.2006, 45, 938; rated as very important paper. NSC 94-2113-M-027-003, (SCI:10.031, 4/128) B. Using other affiliation to publish 14. Norman Lu,* Joseph S. Thrasher,Stefan von Ahsen, Helge Willner,* Drahomir Hnyk, and Heinz Oberhammer*“Pentafluoronitrosulfane, SF5NO2” Inorganic Chem.2006, 45, 1783 (SCI:4.123, 4/43) 15. Howell*, J. L., Lu, N, Friesen, C. M. “New Derivatives of poly-Hexafluoropropylene Oxide from the Corresponding Alcohol”; J. Fluorine Chem. 2005.126, 281-288 (SCI: 1.513, 20/43) 16. Howell*, J. L., Lu, N.; Perez, E. W.; Howell, J. L.; Friesen C. M.; Novak, I.; Waterfeld, A.; Thrasher, J. S., “The Preparation of Primary Poly-Hexafluoropropylene Oxide Halides (Poly-HFPO-CF2X where X = I, Br, Cl and F)” J. Fluorine Chem. 2004.125,1513-1518 (SCI: 1.513) 17. DesMarteau, D. D., Lu, N., Zimmerman* P., Miller* D.; “Polymers Based on a Novel 1,3-perfluorodioxole for Use as a Soft Polymer Pellicle in 157nm Lithography” J. of Photopolymer Science and Technology, 2004,vol. 17, 651-654. (SCI: 0.835 ; 43/74)

  19. International Meeting • 1. “Fluorous Catalysis of Pd-catalyzed Heck Reaction under Thermomorphic Condition without Fluorous Solvents: Facile Liquid/Solid Pd Catalyst Separation at RT" The 2nd International Symposium on Fluorous Technologies (ISoFT07), Yokohama, Japan, July 29-Aug.1, 2007. (oral); (NSC 95-2113-M-027-002) • 2. “High Fluorine Content Bis(fluoro-ponytailed) Bipyridine Ligands for Pd-catalyzed Mizoroki-Heck Reactions under Fluorous Biphasic Catalysis Conditions” The 2nd International Symposium on Fluorous Technologies (ISoFT07), Yokohama, Japan, July 29-Aug.1, 2007. (poster); (NSC 95-2113-M-027-002) • “The study of using novel Cu complexes with fluoro-ponytailed bipyridine for the ATRP under thermomorphic mode” The 2nd International Symposium on Fluorous Technologies (ISoFT07), Yokohama, Japan, July 29-Aug.1, 2007. (poster); (NSC 95-2113-M-027-002) • 4. “New Bis(fluoro-ponytailed) Bipyridine Ligands for the Pd-catalyzed Heck-type Reactions under Fluorous Biphasic and Thermophoric Conditions” The 2nd International Symposium on Fluorous Technologies (ISoFT07), Yokohama, Japan, July 29-Aug.1, 2007 (poster); (NSC 95-2113-M-027-002) • 5. “Copper-catalyzed aerobic oxidation of alcohol under FBS and thermomorphic system” The 2nd International Symposium on Fluorous Technologies (ISoFT07), Yokohama, Japan, July 29-Aug.1, 2007. (poster); (NSC 95-2113-M-027-002)

  20. 6. “New Bis(fluoro-ponytailed) Bipyridine Ligands for the Pd-catalyzed Heck Reactions under Fluorous Biphasic Catalysis Condition” The 18th Winter Fluorine Conference (oral), St. Pete, FL, USA, Jan 14-20, 2007 (NSC 95-2113-M-027-002) • 7. “New Bis(fluoro-ponytailed) Bipyridine Ligands for the Cu‑catalyzed Aerobic Oxidation of Alcohols under Homogeneous or Fluorous Biphasic System” The 18th Winter Fluorine Conference (poster), St. Pete, FL, USA, Jan 14-20, 2007 (NSC 95-2113-M-027-002) • 8. ‘Synthesis, Structure and Reactivity of PdCl2[4,4'-Bis-RfCH2OCH2-2,2'-bpy] (Rf= C3F7, HC4F8, HC8F16 and C10F21)” The 18th ISFC- International Symposium on Fluorine Chemistry (Bremen, Germany, July 30- Aug.4, 2006) 國科會計 畫編號 NSC 94-2113-M-027-003 • 9. “Using α,ω-Perfluoroalkane Bis-sulfonyl Fluorides (FSO2C4F8SO2F, FSO2C6F12SO2F) as monomers And The Application of Their Condensation Polymers For Solid Lithium Battery Electrolyte” the 17th International Symposium on Fluorine Chemistry (July 24-29, 2005) 國科會計畫編號 NSC • 93-2113-M-027-005 • 10. Deparmental Seminar “Two Industrial Applications of Fluoropolymers: Perfluoropolyalkylethers annd Lithium Battery Electrolytes” Univ. of Alabama, USA, Feb. 1, 2005.

  21. 歷年參與之研究計畫

  22. 榮譽獎項及其他 榮獲國立台北科技大學工程學院97年度優等研究獎。 2007.8升副教授。 指導研究生學生林原週、陳宗琦及陳世傑投稿國際會議(The 2nd International Symposium of Fluorous Technology; ISoFT )被接受；且每位學生獲得國科會3萬元之補助，去參與會議。

  23. Invitation • You are cordially invited to join this group for the cutting-edge research.

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