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Learn about partial pressures, Dalton’s Law, and collecting wet gases through water vapor. Explore the ideal gas law for gas mixtures, the calculation of total pressure, and the impact of water vapor on gas collections.
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Unit 7.5 Gas Mixtures: Partial Pressures and Mole fractions
VI) (7.5) Gas Mixtures: Partial Pressures and Mole fractions iii) are the pressures of the gases if they were alone. and a) Introduction: i.) The ideal gas law applies to pure gases and gas mixtures ii) For a mixture of two gases (A and B), the total pressure is given by the expression: These are called partial pressures iv) So: Ptot = PA + PB v) This is referred to as Dalton’s Law of partial pressures: The total pressure of a gas mixture is the sum of the partial pressures of the components of the mixture.
VI) (7.5) Gas Mixtures: Partial Pressures and Mole fractions b) Wet Gases; Partial pressure of water: i) When any gas is collected by bubbling through water, it picks up water vapor. ii) Dalton’s law of partial pressures can be applied to the resulting gas mixture: 1) Ptot = Pwater + Pother 2) Pwater is a fixed value at any given temperature. (appendix 1)