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Esters

Esters. Identify the family of organic compound under CARBONYL group and give the IUPAC & COMMON name D’ structure. 19. 20. 13. 11. 18. 17. 16. 01. 15. 14. 07. 08. 03. 04. 05. 12. 09. 10. 06. 02. 00. O ║. Lactic Acid . CH 3 – CH – C – OH . OH.

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Esters

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  1. Esters

  2. Identify the family of organic compound under CARBONYL group and give the IUPAC & COMMON name D’ structure. 19 20 13 11 18 17 16 01 15 14 07 08 03 04 05 12 09 10 06 02 00 O ║ Lactic Acid CH3 – CH – C – OH OH 2 – hydroxypropanoic acid

  3. Identify the family of organic compound under CARBONYL group and give the IUPAC or COMMON name D’ structure. 19 20 13 11 07 14 15 08 16 17 18 01 10 03 05 04 09 12 06 02 00 O ║ C 3HC CH3 3,3 – dimethylbenzophenone

  4. Identify the family of organic compound under CARBONYL group and give the IUPAC & COMMON name D’ structure. 19 20 13 11 18 17 16 01 15 14 07 08 03 04 05 12 09 10 06 02 00 O ║ C – H CH3 – (CH2)3 – C – CH – CH3 2 – isopropylhexanal CH3 α – isopropylcaproaldehyde

  5. Identify the family of organic compound under CARBONYL group and give the IUPAC or COMMON name D’ structure. 19 20 13 11 15 14 08 07 18 17 16 01 06 03 12 04 09 05 10 00 02 O ║ C – OH Cl Cl O ║ HO – C O ║ C – OH Cl 2,4,6 – trichloro – 1,3,5 – benzenetricarboxylic acid

  6. Identify the family of organic compound under CARBONYL group and give the IUPAC or COMMON name D’ structure. 19 20 13 11 07 14 15 08 16 17 18 01 10 03 05 04 09 12 06 02 00 HO O ║ C – CH3 3HC 3 – hydroxy – 5 – methylacetophenone

  7. Identify the family of organic compound under CARBONYL group and give the IUPAC & COMMON name D’ structure. 19 20 13 11 18 17 16 01 15 14 07 08 03 04 05 12 09 10 06 02 00 O ║ C – H CH3 – C – CH2 – CH – CH2 – CH3 3HC (CH2)2 – CH3 4 – ethyl – 2,2 – dimethylheptanal γ – ethyl – α,α – dimethylenanthaldehyde

  8. ESTERS

  9. An esteris an organic compound that is formed when an alcohol reacts with an acid. FANCYFRUITYFRAGRANTESTERS:Esters are chemicals that have distinctive (usually pleasant) aromas..

  10. preparation

  11. ESTERIFICATION GEN. FORMULA Carboxylic acid + Alcohol → ESTER + Water H+/ heat Example O ║ O ║ H+/ heat CH3 – C – OH + H –O – CH3 CH3 – C – O – CH3 + H2O Acetic acid methanol methyl acetate methyl ethanoate

  12. NOMENCLATURE

  13. IUPACRULES • An ESTER is named as two words. • The first word is the alkyl group attached to the oxygen of the ESTER group. • The ending ic acid will be replaced with the suffix ate. • The common name which is used more often uses the common name of the carboxylic acid.

  14. STRUCTURE 1 19 20 13 11 07 14 15 08 16 17 18 01 10 03 05 04 09 12 06 02 00 O ║ CH3 – (CH2)2 – C – O – CH2 – CH3 ethyl butanoate ethyl butyrate

  15. STRUCTURE 2 19 20 13 11 16 01 18 17 08 14 15 07 09 06 03 12 04 05 10 02 00 O ║ CH3 – (CH2)2 – C – O – CH2 - SH methylthiobutanoate methylthio butyrate

  16. 19 20 13 11 STRUCTURE 3 16 01 18 17 08 14 15 07 09 06 03 12 04 05 10 02 00 O ║ CH3 – (CH2)2 – C – O –– CH3 methyl butanoate methyl butyrate

  17. 19 20 13 11 STRUCTURE 4 16 01 18 17 08 14 15 07 09 06 03 12 04 05 10 02 00 O ║ CH3 – C – O – (CH2)7 – CH3 octylethanoate octyl acetate

  18. STRUCTURE 5 19 20 13 11 16 01 18 17 08 14 15 07 09 06 03 12 04 05 10 02 00 O ║ C – O – CH3 NH2 methyl – 2 – aminobenzoate 2 – (aminomethyl) benzoate

  19. STRUCTURE 6 19 20 13 11 15 14 08 07 18 17 16 01 12 04 09 05 10 06 03 02 00 O ║ CH3 CH3 – C – O – (CH2)2 – CH – CH3 isoamylethanoate isoamyl acetate

  20. 19 20 13 11 18 17 16 01 15 14 07 08 10 03 04 12 06 09 05 STRUCTURE 7 02 00 O ║ CH3 – (CH2)2 – C – O – CH2 – benzyl butanoate benzyl butyrate

  21. STRUCTURE 8 19 20 13 11 15 14 08 07 18 17 16 01 12 04 09 05 10 06 03 02 00 O ║ CH3 H – C – O – CH2 – CH – CH3 isobutyl methanoate isobutyl formate

  22. 19 20 13 11 STRUCTURE 9 16 01 18 17 08 14 15 07 09 06 03 12 04 05 10 02 00 O ║ CH3 – C – O – CH2 – benzyl ethanoate benzyl acetate

  23. 19 20 13 11 STRUCTURE 10 16 01 18 17 08 14 15 07 09 06 03 12 04 05 10 02 00 O ║ CH3 – (CH2)2 – C – O – (CH2)4 – CH3 pentylbutanoate pentyl butyrate

  24. 19 20 13 11 STRUCTURE 11 16 01 18 17 08 14 15 07 09 06 03 12 04 05 10 02 00 O ║ CH3 – C – O – (CH2)2 – CH3 propylethanoate propyl acetate

  25. STRUCTURE 12 19 20 13 11 15 14 08 07 18 17 16 01 12 04 09 05 10 06 03 02 00 O ║ C – O CH2 – CH3 ethyl benzoate ethyl benzoate

  26. Tutti fruity

  27. 19 20 13 11 STRUCTURE 13 15 14 08 07 18 17 16 01 12 04 09 05 10 06 03 02 00 O ║ CH3 – C – O – CH2 – CH3 ethylphenylethanoate ethylphenyl acetate

  28. APPLICATIONS

  29. FOOD flavoring

  30. COSMETICS flavoring

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