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Explore the concept of pH in pure water and chemical solutions, including the relationship between hydronium and hydroxide ions, the ion product constant Kw, and calculations to determine pH and pOH levels.
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Pure Water is Neutral Pure water contains small, but equal amounts of ions: H3O+ and OH- H2O + H2O H3O+ + OH- hydronium hydroxide ion ion 1 x 10-7 M1 x 10-7 M H3O+ OH-
[H3O+ ] = [OH-] = 1 x 10-7 M • Since they are equal, a neutral solution results from water • Kw = [H3O+ ] x [OH-] = 1 x 10-14M2 • Kw is called the “ion product constant” • The equation is applicable to pure water and aqueous solutions
pH and pOH • pH = -log [H3O+] • pOH = -log [OH-] • pH + pOH = 14 • [H3O+] = antilog -pH
100 10-1 10-3 10-5 10-7 10-9 10-11 10-13 10-14 14 13 11 9 7 5 3 1 0 10-14 10-13 10-11 10-9 10-7 10-5 10-3 10-1 100 [H+] pH 0 1 3 5 7 9 11 13 14 Acidic Neutral Basic pOH [OH-]
Using Kw The [OH- ] of a solution is 1.0 x 10- 3M. What is the [H3O+]? Kw = [H3O+ ] [OH- ] = 1.0 x 10-14 M2 [H3O+] = 1.0 x 10-14 M2 [OH-] [H3O+] = 1.0 x 10-14 M2= 1.0 x 10-11 M 1.0 x 10- 3 M
Using the Calculator 1.0 x 10 -14 1.0 x 10-3 Enter1.0 EE +/- 14 1.0 EE+/- 3 = 1.0 x 10 -11
Find the hydroxide ion concentration of 3.0 10-2 M HCl. [H3O+][OH-] = 1.0 10-14 [3.0 10-2][OH-] = 1.0 10-14 [OH-] = 3.3 10-13 M Acidic or basic? Acidic
pH In the expression for [H3O+] 1 x 10-exponent the exponent = pH [H3O+] = 1 x 10-pH M
Some [H3O+] and pH [H3O+] pH 1 x 10-5 M 5 1 x 10-9 M 9 1 x 10-11M 11
Learning Check The pH of a soap is 10. What is the [H3O+] of the soap solution? [H3O+] = 1 x 10-pH M = 1 x 10-10 M
pH on the Calculator [H3O+] is 4.5 x 10-6 M pH = ? pH = -log [H3O+] pH = 4.5 EXP(or EE) 6 +/- LOG +/- = 5.3
pH Scale • What is the pH of 0.050 M HNO3? pH = -log[H3O+] pH = -log[0.050] pH = 1.3 Acidic or basic? Acidic
pH Scale • What is the molarity of HBr in a solution that has a pOH of 9.6? • [H3O+] = antilog -pH pH + pOH = 14 pH + 9.6 = 14 pH = 4.4 pH = -log[H3O+] 4.4 = -log[H3O+] -4.4 = log[H3O+] [H3O+] = 4.0 10-5 M HBr Acidic
Learning Check Identify each solution as 1. acidic 2. basic 3. neutral A. _1__ HCl with a pH = 1.5 B. _2__ Pancreatic fluid [H+] = 1 x 10-8 M C. _1__ Sprite soft drink pH = 3.0 D. _3__ pH = 7.0 E. _1__ [OH-] = 3 x 10-10 M F. _2__ [H+] = 5 x 10-12 M