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Biochemical Pathways Involving PpLOX and PpAOS in Non-Enzymatic Hydrolysis and Cyclization

This study explores the roles of various enzymes, including PpLOX1, PpLOX2, PpAOS1, and PpAOS2, as well as non-enzymatic processes in the hydrolysis and cyclization of fatty acid derivatives. We examine the formation of key compounds such as 12,13-EOT, 11,12-EETE, and cyclopentenone derivatives, emphasizing the significance of α-ketols and γ-ketols in plant metabolism. Understanding these pathways enhances our knowledge of plant biochemistry and their responses to environmental stimuli.

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Biochemical Pathways Involving PpLOX and PpAOS in Non-Enzymatic Hydrolysis and Cyclization

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  1. 18:3 (n-3) 20:4 (n-6) PpLOX1 PpLOX2 PpLOX1-7 13S-HPOTE 12S-HPETE PpAOS1 PpAOS2 PpAOS1 PpAOS2 Non-enzymatic Hydrolysis and Cyclization Non-enzymatic Hydrolysis and Cyclization 12,13-EOT 11,12-EETE PpAOC1 PpAOC2 PpAOC2 α-ketols γ-ketols Racemic cyclopentenone α-ketols γ-ketols Racemic cyclopentenone cis-(+)-OPDA 11-OPTA

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