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Chronologies from radiocarbon dates to age-depth models

Bio 351 Quantitative Palaeoecology. Chronologies from radiocarbon dates to age-depth models. Lecture Plan Calibration of single dates 14 C years  cal years Bayesian statistics Calibration of multiple dates in a series at the same event Age-depth models. Richard Telford.

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Chronologies from radiocarbon dates to age-depth models

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  1. Bio 351 Quantitative Palaeoecology Chronologiesfrom radiocarbon dates to age-depth models • Lecture Plan • Calibration of single dates • 14C years  cal years • Bayesian statistics • Calibration of multiple dates • in a series • at the same event • Age-depth models Richard Telford

  2. Radiocarbon Dating 14C half-life is 5730 years Suitable for organic material and carbonates Useful for sediments 200 - 50 000 years old The most widely used dating tool for late-Quaternary studies Unique amongst absolute-dating methods in not giving a date in calendar years

  3. Radioactive Decay 14C→14N+b Random process Atom has 50% chance of decaying in 5730 yrs Exponential decay

  4. Radioactive Decay equations What is λ?

  5. Using Radioactive Decay equations Express measured 14C as %modern A=Ainitiale-ln(2)*age/halflife ln(A/Ainitial)=ln(2)*age/halflife Use Libby halflife 5568 age= -8033 ln(A/Ainitial) assume Ainitial = Amodern age= -8033 ln(A/Amodern) Assumes atmospheric 14C constant

  6. Causes of Non-Constant Atmospheric 14C 1) Changes in production - Variations in solar activity solar maximumstrong magnetic shieldminimum 14C production solar minimum weak magnetic shieldmaximum 14C production - Variations in earth magnetic field strength 2) Changes in distribution - rate of ocean turnover- global vegetation changes

  7. Dendrochronological Evidence Find 14C date of tree rings of known age

  8. INTCAL04

  9. 14C Calibration Curves Atmospheric Marine

  10. Calibration: from 14C Age to Calibrated Age • The intercept method • quick, easy and entirely inappropriate • Classical calibration (CALIB) • fast and simple • Bayesian calibration • allows use of prior information

  11. Calibration of marine dates Use either classical or Bayesian calibration Use the marine calibration curve Set ΔR – the local reservoir affect offset Set σΔR – the uncertainty Do not subtract R

  12. The Intercept Method: Multiple Intercepts 4800 4700 4600 Radiocarbon years BP 4530±50 4500 4400 4300 4200 4800 5000 5200 5400 5600 Calibrated years BP 4540±50 ? 5295

  13. The Intercept Method: Missing Probabilities

  14. Classical Calibration • Unknown calendar date m(q) is the true radiocarbon age, but cannot be measured precisely Radiocarbon date y is a realisation of Y = m(q) + noise Noise is assumed to have a Normal distribution with mean 0, and standard deviation s. Thus Y~N(m(q), s2).

  15. Classical Calibration Normal Distribution The probability distribution p(Y) of the 14C ages Y around the 14C date y with a total standard deviation s is: Total standard deviation s is, where ss and sc are the standard deviations of the 14C date and calibration curve respectively: The calibration curve can be defined as: Replacing Y with m(q), p(Y) is: Y = m(q) To obtain P(q), m(q) is determined for each calendar year and the corresponding probability is transferred to the q axis.

  16. Classical Calibration Quick and simple Fine if we just have one date But difficult to include any a priori knowledge e.g. dates in a sequence To do this we need to use the Bayesian paradigm

  17. The Bayesian Paradigm (1702-1761) Bayes, T.R. (1763) An essay towards solving a problem in the Doctrine of Chances. Philosophical Transactions of the Royal Society, 53: 370-418. Can utilise information outside of the data. This prior information and its related uncertainty must be encoded into probabilities. Then it can be combined with data to assess the total value of the combined information. Bayes' Theorem provides a structure for doing this. Simple in theory, but computationally difficult.

  18. The Bayesian Paradigm The Likelihood - “How likely are the values of the data observed, given some specific values of the unknown parameters?” The Prior – “How much belief do I attach to possible values of the unknown parameters before observing the data?” The Posterior - “How much belief do I attach to possible values of the unknown parameters after observing the data?” The PosteriorThe Likelihood The Prior

  19. The Likelihood • Unknown calendar date m(q) is the true radiocarbon age, but cannot be measured precisely Radiocarbon date y is a realisation of Y = m(q) + noise Noise is assumed to have a Normal distribution with mean 0, and standard deviation s. Thus Y~N(m(q), s2). With the calibration curve, we have an estimate of m(q), and can formalise the relationship between q and y±s This is the likelihood.

  20. The Prior For a single date with weak (or no) a priori information we can use an non-informative prior e.g. for a date q known to be post-glacial Pprior(q)= Often we know more than this. Perhaps there is stratigraphic information:e.g. dates q1, q2 & q3 are taken from a sediment core and are in chronological order Pprior(q1<q2<q3)= The Bayesian paradigm offers the greatest advantage over classical methods when there is a strong prior and overlapping data. constant for -50<q<14000 0 otherwise constant for a<q1<q2<q3<b 0 otherwise

  21. Computation of the Posterior Analytically calculation is impossible for all but the simplest cases So instead Produce many simulations from the posterior and use as estimate Markov Chain Monte Carlo does this to give approximate solution Markov Chain? - each simulation depends only on the previous one - selected from range of possible values - the state space Areas with higher probability will be sampled more frequently

  22. Markov Chain Continued • Start with an initial guess • Select the next sample • Repeat step 2 until convergence is reached Gibbs sampler - one of the simplest MCMC methods

  23. Convergence theta[1] chains 1:2 150.0 100.0 50.0 0.0 1 2000 4000 iteration Easier to diagnose that it hasn’t converged, than prove that it has.

  24. Reproducibility MCMC does not yield an exact answer It is the outcome of random process Repeated runs can give different results Calibrate multiple times & verify results are similar Report just one run Acknowledge level of variability

  25. Outlier Detection • Outliers can have a large impact on the age estimates • Extreme but “correct” dates • Contamination • Erroneous assumptions? • Need a method to detect them and reduce their influence • Outliers can only be defined based on calibrated dates • Christen (1994) • Radiocarbon determinations dating the same event should come from N(m(q), s2) • An outlier is a determination that needs a shift dj • Given the a priori probability that a date is an outlier, posteriori probabilities can be calculated • Calibration and outlier detection done together • Automatic down-weighting of outliers

  26. Dates in Stratigraphic Order

  27. Wiggle Matching 20 years q1 q2 In material with annual increments (tree-rings & varves) Time between two dates precisely known This additional information can be used in the prior

  28. Wiggle Matching 2 Buck et al. (1996) Bayesian approach to interpreting archaeological data. Wiley: Chichester. p232-238

  29. Wiggle Matching in Unlaminated Sediments Dx12 Dx23 q1 q2 q3 If the sedimentation rate is assumed to be constant: (q1-q2)/(q2-q3)= Dx12/Dx23 This information can be used in the prior

  30. Wiggle Matching in Unlaminated Sediments Christen et al. (1995) Radiocarbon 37 431-442 • Wiggle matching has greatest impact when • the calibration curve is very wiggly • there is a high density of dates • But may be sensitive to the assumption of linear sedimentation

  31. Sensitivity Tests Bayesian radiocarbon calibration is very flexible and sensitive Apparently small changes in prior information can have a large effect on the results Need to carefully consider the specific representations you choose And investigate what happens when you vary them Report the findings

  32. Software • Oxcal • Download from http://www.rlaha.ox.ac.uk/orau/oxcal.html • Fast & easy for simple models • BCAL • Online at http://bcal.shef.ac.uk • Automatic outlier detection • WinBugs • If you want to implement a novel model • Remember to enter your samples oldest first!

  33. From Dates to Chronologies • Not every level dated • too expensive • insufficient material • Fit age-depth to find undated levels • Linear interpolation • Linear regression models • Splines • Mixed-effect models (Heegaard et al. (2005)) Age-depth models based on uncalibrated dates are meaningless

  34. Linear Interpolation Lake Tilo What assumptions does this make?

  35. Linear Interpolation – Join the Dots Which dots? 285 BP

  36. Linear regression models Lake Tilo Also weighted-least squares Assess by c2 Polynomial order What assumptions does this make?

  37. Is Sedimentation a Polynomial Function? Holzmaar varve sequence

  38. Conclusions Bayesian calibration of 14C dates - allows inclusion of prior knowledge - produces more precise calibrations - but, if the priors are invalid, lower accuracy Age-depth modelling - lots of different methods - some are worse than others - no currently implemented method properly incorporates the full uncertainties

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