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Calculations in Chapter 10

Calculations in Chapter 10. Molar Enthalpy of Fusion. Used when melting or freezing = ___ energy ____ mol of substance Can be arranged to find any of the three Units for molar enthalpy of fusion will be kJ/mol and units for energy is kJ or J, (kilojoules or joules).

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Calculations in Chapter 10

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  1. Calculations in Chapter 10

  2. Molar Enthalpy of Fusion • Used when melting or freezing • = ___energy ____ mol of substance • Can be arranged to find any of the three • Units for molar enthalpy of fusion will be kJ/mol and units for energy is kJ or J, (kilojoules or joules)

  3. Example Problem • The molar heat of fusion for water is 6.009 kJ/mol. How much energy is needed to convert 60.0 g of ice at 0°C to liquid water at 0°C? • Rearrange the formula for energy • Energy =  mol of substance

  4. Have to convert the 60.0 g of ice to mol • Divide by the molar mass of water • 60.0 g/ 18.016 g/mol = • 3.330373002 mol H2O(s) • Energy = 6.009 kJ/mol 3.330373002 mol H2O(s) = • 20.01221137 kJ • 20.0 kJ needed to convert 60.0 g of ice at 0°C to liquid water at 0°C

  5. Molar Enthalpy of Vaporization • Used when boiling or condensing • = energy mol of substance • Can be arranged to find any of the three • Boiling has energy required, condensing gives off energy

  6. Example Problem • How much heat is evolved when 275 g of ammonia gas condenses to a liquid at its boiling point? The molar enthalpy of vaporization for ammonia is 23.3 kJ/mol • Have to convert the g of ammonia to mol of ammonia • 275 g/ 17.034 g/mol = 16.14418222mol

  7. Rearrange the formula for energy evolved • Energy =  mol of substance • Energy = 23.3 kj/mol 16.14418222mol • Energy = 376.1594458 kJ • Energy = 376 kJ

  8. Another Problem • What mass of steam is required to release 4.97 x 105 kJ of heat energy on condensation? The molar enthalpy of vaporization for water is 40.79 kJ/mol • First rearrange to solve for mol • Solve for mol • Multiply by the molar mass to find grams • Answer: 2.20 x 105 g H2O

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