What’s New in Water Treatment?

1. What’s New in Water Treatment? How well could filters remove Particles? Coagulants and Filter Aids Sticky Particles and Sticky Media

2. Filter Performance Models • Iwasaki (1937) developed relationships describing the performance of deep bed filters. C is the particle concentration [number/L3] l0 is the initial filter coefficient [1/L] z is the media depth [L] The particle’s chances of being caught are the same at all depths in the filter; pC* is proportional to depth

3. Filtration Performance: Dimensional Analysis • What is the parameter we are interested in measuring? _________________ • How could we make performance dimensionless? ____________ • What are the important forces? Effluent concentration C/C0 or pC* Only effective in the attachment phase Electrostatic London van der Waals Inertia Viscous Gravitational Thermal Need to create dimensionless force ratios!

4. Gravitational Thermal Viscous Viscous Choose viscosity as the common force that inhibits transport • We will use viscosity as the repeating parameter and create a set of dimensionless force ratios But these forces are functions of …

5. Gravity forces velocities v pore Gravity only helps when the streamline has a _________ component. horizontal Use this equation

6. Diffusion (Brownian Motion) v pore Diffusion velocity is high when the particle diameter is ________. kB=1.38 x 10-23 J/°K T = absolute temperature small dc is diameter of the collector

7. Geometric Parameters • What are the length scales that are related to particle capture by a filter? • ______________ • __________________________ • ______________ • Porosity (void volume/filter volume) (e) • Create dimensionless groups • Choose the repeating length ________ Filter depth (z) Collector diameter (media size) (dc) Particle diameter (dp) (dc) Number of collectors!

8. Write the functional relationship attachments per contact Length ratios Force ratios doubles If we double depth of filter (or a) what does pC* do? ___________ How do we get more detail on this functional relationship? Empirical measurements Numerical models

9. 20 cm/hr 0.2 mm sand 1 m deep Particle density of 1040 kg/m3 Total removal (SSF conditions) Plots based on numerical models

10. How deep must a filter (SSF) be to remove 99% of bacteria? • Assume a is 1 and dc is 0.2 mm, V0 = 20 cm/hr • For 1 m of sand pC*=____ • Depth for pC* of ____ is _____ • What does this mean? 20 2 10 cm If the attachment efficiency were 1, then we could get great particle capture in a 1 m deep filter!

11. Total removal (RSF conditions) • dc=0.5 mm • Approach velocity is 5 m/hr • 1 m deep • Particle density of 1040 kg/m3

12. How deep a Rapid Sand Filter will remove 90% of cryptosporidium? • Assume a is 1 and dc is 0.5 mm, V0 = 5 m/hr • dp is 4 mm • pC* is ____ for 1 m deep filter • z is ________________ 1.8 1 m/1.8=0.55 m We need flocculation to produce larger and more dense particles to get good removal in RSF

13. Slow Sand Filtration • First filters to be used on a widespread basis • Fine sand with an effective size of 0.2 mm • Low flow rates (10 - 40 cm/hr) • Schmutzdecke (_____ ____) forms on top of the filter • causes high head loss • must be removed periodically • Used without coagulation/flocculation! filter cake

14. Typical Performance of SSF Fed Cayuga Lake Water 1 Fraction of influent E. coli remaining in the effluent 0.1 0.05 0 1 2 3 4 5 Time (days) (Daily samples) Filter performance doesn’t improve if the filter only receives distilled water

15. How do Slow Sand Filters Remove Particles? • How do slow sand filters remove particles including bacteria, Giardia cysts, and Cryptosporidium oocysts from water? • Why does filter performance improve with time? • Why don’t SSF always remove Cryptosporidium oocysts? • Is it a biological or a physical/chemical mechanism? • Would it be possible to improve the performance of slow sand filters if we understood the mechanism?

16. Slow Sand Filtration Research Apparatus Manometer/surge tube Cayuga Lake water (99% or 99.5% of the flow) Manifold/valve block Peristaltic pumps Sampling Chamber Auxiliary feeds (each 0.5% of the flow) Sampling tube Lower to collect sample To waste 1 liter sodium azide 1 liter E. coli feed Filter cell with 18 cm of glass beads

17. Quiescent Cayuga Lake water 1 Sodium azide (3 mM) Control 0.1 0.05 0 2 4 6 8 10 Time (days) Biological and Physical/Chemical Filter Ripening Continuously mixed Cayuga Lake water 1 Physical/chemical Fraction of influent E. coli remaining in the effluent Gradual growth of _______ or ________ 0.1 biofilm predator 0.05 0 1 2 3 4 5 Time (days) What would happen with a short pulse of poison?

18. 1 Control Sodium azide pulse Sodium chloride pulse 0.1 0.08 0 1 2 3 4 5 6 Time—h Biological Poison Biofilms? Abiotic? q Fraction of influent E. coli remaining in the effluent predators Grazers or suspension feeders? ___________________________ are removing bacteria Suspension feeding predators

19. Chrysophyte long flagellum used for locomotion and to provide feeding current short flagellum 1 µm stalk used to attach to substrate (not actually seen in present study)

20. Particle Removal by Size 1 control 3 mM azide 0.1 Recall quiescent vs. mixed? Fraction of influent particles remaining in the effluent Effect of the Chrysophyte 0.01 What is the physical-chemical mechanism? 0.001 0.8 1 10 Particle diameter (µm)

21. Role of Natural Particles in SSF • Could be removal by straining • But SSF are removing particles 1 mm in diameter! • To remove such small particles by straining the pores would have to be close to 1 mm and the head loss would be excessive • Removal must be by attachment to the sticky particles!

22. Particle Capture Efficiency • Sand filters are inefficient capturers of particles • Particles come into contact with filter media surfaces many times, yet it is common for filters to only remove 90% - 99% of the particles. • Failure to capture more particles is due to ineffective __________ • Remember the diffusion surprise? attachment

23. Techniques to Increase Particle Attachment Efficiency • Make the particles stickier • The technique used in conventional water treatment plants • Control coagulant dose and other coagulant aids (cationic polymers) • Make the filter media stickier • Potato starch in rapid sand filters? • Biofilms in slow sand filters? • Mystery sticky agent imported into slow sand filters?

24. Mystery Sticky Agent • Serendipity! • Head loss through a clogged filter decreases if you add acid • Maybe the sticky agent is acid soluble • Maybe the sticky agent will become sticky again if the acid is neutralized • Eureka!

25. Attachment Mediating Polymer (AMP) • Concentrate particles from Cayuga Lake • Acidify with 1 N HCl • Centrifuge • Centrate contains polymer • Neutralize to form flocs

26. AMP Characterization Alum! Did I discover alum?

27. Which part of AMP is the important actor? • What causes the particle removal? • Alum • Iron • the organic matter (the volatile solids) or a • Combination of Al and organic matter

28. The dilution delay • Students compared filters treated with AMP, aluminum, and iron • They used the amount of aluminum and iron that was in the AMP • Found that AMP was far superior • We concluded _______________________________ • 4 years later we discovered that they had made a dilution error and hadn’t actually applied nearly as much aluminum and iron as was present in the AMP • Further experimentation revealed that alum improves filter performance just like AMP the organic matter was significant

29. E. coli Removal as a Function of Time and Al Application Rate No E. coli detected Log remaining is proportional to accumulated mass of Al in filter

30. Head Loss Produced by Al

31. Aluminum feed methods • Alum must be dissolved until it is blended with the main filter feed above the filter column • Alum flocs are ineffective at enhancing filter performance • The diffusion dilemma (alum microflocs will diffuse efficiently and be removed at the top of the filter)

32. Performance Deterioration after Al feed stops? • Hypotheses • Decays with time • Sites are used up • Washes out of filter • Research results • Not yet clear which mechanism is responsible – further testing required

33. Sticky Media Potentially treat filter media at the beginning of each filter run No need to add coagulants to water for low turbidity waters Filter will capture particles much more efficiently Sticky Particles Easier to add coagulant to water than to coat the filter media Sticky Media vs. Sticky Particles

34. Future Work • Develop application techniques to optimize filter performance • How can we coat all of the media? • Will the media remain sticky through a backwash? • Will it be possible to remove particles from the media with a normal backwash? • What are the best ways to use aluminum as a filter aid in SSF and in RSF?

35. Conclusions • Filters could remove particles more efficiently if the _________ efficiency increased • SSF remove particles by two mechanisms • ____________ • _______________________ • Log remaining is proportional to accumulated mass of alum in filter attachment Predation Naturally occurring aluminum

36. Polymer in a void between glass beads

37. Polymer in a void between glass beads

38. Polymer on and bridging between glass beads

39. Polymer Bridge between Glass Beads

40. How can we make filter media sticky?Why do slow sand filters work? • Slow sand filters don’t use any coagulants, yet their performance improves with time • Their improved performance is due to natural particulate matter that is captured by the filter • What is it about this particulate matter that makes the filters work better?