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Chapter 3 The second law

Chapter 3 The second law

Chapter 3 The second law. A spontaneous direction of change: the direction of change that does not require work to be done to bring it about. 3.1 The second law.

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ITK-233 Termodinamika Teknik Kimia I

ITK-233 Termodinamika Teknik Kimia I

ITK-233 Termodinamika Teknik Kimia I. Dicky Dermawan www.dickydermawan.net78.net dickydermawan@gmail.com. 3 sks. 4 - The Second Law: Entropy. Process Direction.

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Chapter 7.

Chapter 7.

Chapter 7. Applications of the Second Law. Consider entropy changes in various reversible (!!!) processes. ?. We have:. ?. (a) Adiabatic process. ?. Hence a reversible adiabatic process is isentropic. ?. (b) Isothermal process :. (c) Change of phase (isothermal and isobaric)

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Entropy

Entropy

Entropy. Cengel & Boles, Chapter 6. Entropy. From the 1st Carnot principle: this is valid for two thermal reservoirs. The Clausius Inequality. For a system undergoing a cycle and communicating with N thermal reservoirs, it can be shown that

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The Carnot cycle

The Carnot cycle

The Carnot cycle. T. a. b. T 2. T 1. c. d. s. Entropy changes in reversible processes. Various cases:. Adiabatic process: ?q r = 0, ds = 0, s = constant. A reversible adiabatic process is isentropic. THIS IS NOT TRUE FOR AN IRREVERSIBLE PROCESS!. Isothermal process:.

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Phase space (reminder)

Phase space (reminder)

Phase space (reminder). Statistics involves the counting of states, and the state of a classical particle is completely specified by the measurement of its position and momentum. If we know the six quantities

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