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Many ligand exchange reactions - PowerPoint PPT Presentation

Each X will increase the oxidation number of metal by +1. Each L and X will supply 2 electrons to the electron count.

Each X will increase the oxidation number of metal by +1. Each L and X will supply 2 electrons to the electron count. Now looking at compounds having a charge of +1 to obey 18 e rule. Elec count: 4 (M) +2 (NO) +12 (L 6 ) = 18. NO + is isoelectronic to CO X increases O N by 1.

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Principal mechanisms of ligand exchange in octahedral complexes

Principal mechanisms of ligand exchange in octahedral complexes. Dissociative. Associative. MOST COMMON. Dissociative pathway (5-coordinated intermediate). Associative pathway (7-coordinated intermediate). Experimental evidence for dissociative mechanisms.

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Many ligand exchange reactions - PowerPoint PPT Presentation

Each X will increase the oxidation number of metal by +1. Each L and X will supply 2 electrons to the electron count.

Principal mechanisms of ligand exchange in octahedral complexes