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Main group metal - PowerPoint PPT Presentation

Each X will increase the oxidation number of metal by +1. Each L and X will supply 2 electrons to the electron count.

Each X will increase the oxidation number of metal by +1. Each L and X will supply 2 electrons to the electron count. Now looking at compounds having a charge of +1 to obey 18 e rule. Elec count: 4 (M) +2 (NO) +12 (L 6 ) = 18. NO + is isoelectronic to CO X increases O N by 1.

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Metal carbonyls may be mononuclear or polynuclear

Metal carbonyls may be mononuclear or polynuclear . Characterization of metal carbonyls. IR spectroscopy. (C-O bond stretching modes). Effect of charge. u (free CO) 2143 cm -1. Lower frequency, weaker CO bond. Effect of other ligands. Increasing elec donating ability of phosphines.

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1.92k views • 48 slides

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Main group metal - PowerPoint PPT Presentation

Each X will increase the oxidation number of metal by +1. Each L and X will supply 2 electrons to the electron count.

Metal carbonyls may be mononuclear or polynuclear