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Keywords ion selective electrode - PowerPoint PPT Presentation

Application of N,N’-bis(pyridine-2-carboxamido)-2-aminobenzylamine in construction of a new Tm3 polymeric membrane io

A PVC membrane containing N,N’-bis(pyridine-2-carboxamido)-2-aminobenzylamine (BPCA) as a suitable ionophore, sodium tetraphenyl borate (NaTPB) as an anionic additive, nitrobenzene (NB) as solvent mediator, exhibits a Nernstian response (slope of 20.4 ± 0.3 decade of activity) for Tm(III) ions over a wide concentration range up to 1.0×10–6 and 1.0×10–2 M, with a detection limit of 6.3×10–7 M in the pH range 2.8–8.3. It has a fast response time (~5 s).

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A Highly Selective and sensitive Lu3 PVC-Membrane Sensor based on Di-tert-butyl-1-(tert-butyl thio)-1,2-hydrazine dicar

Di-tert-butyl-1-(tert-butyl thio)-1,2-hydrazine dicarboxylate (DBHC) was used as a sensing material which plays the role of a suitable ionophore in the creation of a Lu(III) PVC membrane sensor. It shows a Nernstian behavior (with slope of 20.2 ± 0.4 mV per decade) over a wide concentration range (1.0 × 10−6-1.0 × 10−2 M) with the detection limit of 5.8 × 10−7 M. The sensor has a very short response time, in the whole concentration range (~5 s), and can be used in the pH range of 2.9-8.8.

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63 views • 5 slides

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Keywords ion selective electrode - PowerPoint PPT Presentation

Application of N,N’-bis(pyridine-2-carboxamido)-2-aminobenzylamine in construction of a new Tm3 polymeric membrane io

A Highly Selective and sensitive Lu3 PVC-Membrane Sensor based on Di-tert-butyl-1-(tert-butyl thio)-1,2-hydrazine dicar