Insertion reactions - PowerPoint PPT Presentation

Carbenes and Nitrenes: Application to the Total Synthesis of (–)-Tetrodotoxin

Carbenes and Nitrenes: Application to the Total Synthesis of (–)-Tetrodotoxin. Effiette Sauer March 18 th 2004. Hinman, A.; Du Bois, J. J. Am. Chem. Soc. 2003 , 125 , 11510. What are Carbenes? Nitrenes?. Neutral, divalent carbon species containing six valence electrons.

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Lecture 36 Organometallic reactions and catalysis 1) Reactions involving modification of ligands

Lecture 36 Organometallic reactions and catalysis 1) Reactions involving modification of ligands. We will consider: (a) migratory insertion; (b) b -hydride elimination; (c) a -abstraction.

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