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Sharpless Asymmetric Dihydroxylation

Sharpless Asymmetric Dihydroxylation. Standard Dihydroxylation. Possible [3+2] Cycloaddition. (DHQD) 2 PHAL (found in AD-mix b) 1,4-bis(9-O- d i h ydro q uini d ine) phthalizine. Coordination of a chiral amine to the OsO 4 leads to an asymmetric complex.

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Sharpless Asymmetric Dihydroxylation