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Chapter 4 Aqueous Reactions and Solution Stoichiometry

Chapter 4 Aqueous Reactions and Solution Stoichiometry. 4.1 General Properties of Aqueous Solutions. Solutions are homogeneous mixtures of two or more pure substances. The substance present in the greatest quantity is the solvent .

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Nernst equation

Nernst equation. E = E ? - lnQ E ? = - At 25 o C, the Nernst equation can be simplified further: E = E ? - lnQ Under equilibrium condition: Q = K, and E = 0 so lnK = E ? * v /25.7mV . Concentration Cells.

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Concentration Cells

Concentration Cells. M | M + (aq, L) || M + (aq, R) | M Cell reaction: M + (aq, R) ? M + (aq, L) since ? r G ? = 0 (why?). The cell emf. The emf of a cell can be calculated by the difference of the potentials of the two electrodes, E cell = E right - E left

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Cl aq agcl - PowerPoint PPT Presentation

Chapter 4 Aqueous Reactions and Solution Stoichiometry

Nernst equation

Concentration Cells