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Chapter 3 An Introduction to Organic Reactions: Acids and Bases

Chapter 3 An Introduction to Organic Reactions: Acids and Bases. Cleavage of Covalent Bonds Homolysis Heterolysis. Heterolytic reactions almost always occur at polar bonds The reaction is often assisted by formation of a new bond to another molecule. Example

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Carbanions II Carbanions as nucleophiles in S N 2 reactions with alkyl halides.

Carbanions II Carbanions as nucleophiles in S N 2 reactions with alkyl halides. a) Malonate synthesis of carboxylic acids b) Acetoacetate synthesis of ketones c) 2-oxazoline synthesis of esters/carboxylic acids d) Organoborane synthesis of acids/ketones

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Chlorination of Other Alkanes

Chlorination of Other Alkanes. Can you write the complete mechanism for the chlorination of cyclopentane?. initiation. propagation step 1. propagation step 2. termination. overall reaction. Chlorination of Propane - Selectivity.

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416 views • 22 slides

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Carbanions - PowerPoint PPT Presentation

Chapter 3 An Introduction to Organic Reactions: Acids and Bases

Carbanions II Carbanions as nucleophiles in S N 2 reactions with alkyl halides.

Chlorination of Other Alkanes