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Development of a Chiral Lewis Base Catalyzed Allylation Reaction

Development of a Chiral Lewis Base Catalyzed Allylation Reaction. Jason Poulin Barriault Lab March 20 th 2008. Presentation Outline. Generalities Allylation/crotylation reactions Lewis base catalysis (initial trials) Nonlinear effects in asymmetric synthesis Improved catalyst system

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1.58k views • 125 slides

Lecture 33 1) h 3 -Allyl complexes

Lecture 33 1) h 3 -Allyl complexes. h 3 -Allyl ligand C 3 H 5 - is anionic, donates 4 electrons from its p -system to form one s - and one p -bond with the metal and forms complexes with many transition metals such as Ni( h 3 -C 3 H 5 ) 2 .

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2.22k views • 6 slides

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Allyl - PowerPoint PPT Presentation

Development of a Chiral Lewis Base Catalyzed Allylation Reaction

Lecture 33 1) h 3 -Allyl complexes