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S1 PES

Figure 1. Calculated relative energies (kcal/mol) and wavelengths (nm) of vertical excitation and emission for 1,8-Dihydroxy-2-naphthaldehyde in cyclohexane (purple numbers), dichloromethane (red numbers), and acetonitrile (blue numbers). TB*. TS1*. N*. TS2*. TA*. -0.28 -1.25 -1.55.

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