Chemical reactions and equations. I . Chemical Equations. A properly written chemical equation can summarize any chemical change. The following requirements will help you write and read a chemical equation:
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A properly written chemical equation can summarize any chemical change. The following requirements will help you write and read a chemical equation:
A. The equation must represent facts. (Chemical analysis in a laboratory must have been done.)
B. The equation must contain the correct formulas for the reactants (on the left of the arrow) and the products (on the right of the arrow).
C. The law of conservation of mass must be satisfied. (Atoms are neither created nor destroyed in an ordinary chemical reaction.) Therefore the same number of atoms of each element must appear on each side of a correct chemical equation. To equalize the number of atoms, a coefficient is placed in front of a formula to specify the relative number of each compound (or moles of each compound) needed for this reaction.
This is called balancing the equation.
II. Symbols, Hydrocarbons, and Diatomic Molecules Used in Writing and Balancing Equations
(look in notes)
Example: Propane + oxygen carbon dioxide + water
A. Propane – is a hydrocarbon (a combination of hydrogen and carbon), propane is C3H8
B. Oxygen – is a diatomic molecule – in nature oxygen exists as O2. In an equation, if the word oxygen, hydrogen, nitrogen, fluorine, chlorine, bromine, iodine, sulfur, or phosphorus is used you must write it as being diatomic (or polyatomic).
C3H8 + O2 CO2 + H2O
2nd: Now we must balance the equation – first write an atom inventory for the total number of atoms of each element on each side of the equation.
C3H8 + O2 CO2 + H2O Reactants Products # C 3 # C 1 # H 8 # H 2 # O 2 # O 3
Atom Inventory or Counting Atoms – you must be able to count atoms in order to balance an equation. There are two ways to designate numbers in a formula:
1. MgCl2 – 1 atom of Mg and 2 of Cl
2. Sn3N2 – 3 atoms Sn and 2 N
B. Coefficient – the large number in front of the formula of a compound. Tells the number of molecules or formula units or atoms of an element.
Remember that atoms cannot be created or destroyed; we must balance this equation using coefficients. Never change a subscript to balance an equation!!
___C3H8(g) + _5_O2 _3_CO2 + 4_H2O
# C 3 # C 3
# H 8 # H 8
# O 10 # O 10
This now tells us the correct chemical equation and exactly how much of each reactant was needed and how much of each product was produced!!!!
___NaNO3 + ___Pb
___CO2 + ___H2O
4. Iron + sulfur iron (II) sulfide
5. Zinc + copper (II) sulfate zinc sulfate + copper
6. Silver nitrate + sodium bromide silver bromide + sodium nitrate
7. Water , in the presence of electricity and a Pt catalyst decomposes into hydrogen and oxygen
8. Ferric chloride + ammonium hydroxide ferric hydroxide + ammonium chloride
9. Iron + water hydrogen + ferric oxide
10. Potassium hydroxide + phosphoric acid potassium phosphate + water
11. Methane gas reacts with oxygen gas to produce carbon dioxide gas, gaseous water, and energy.
12. ___PbCl2(aq) + ___Na2CrO4(aq) ___PbCrO4(s) + ___NaCl(aq)
13. ___Al2(SO4)3 (aq) + ___Ca(OH)2 (aq) ___Al(OH)3(s) + ___CaSO4(s)
Some reactions require more energy then is produced; others produce more energy then is required.
A. Exothermic Reaction: a reaction that releases energy; energy is a product and is written on the right side of the arrow.
B. Endothermic Reaction: a reaction that absorbs energy; energy is a reactant and is written on the left of the arrow.
KE = ½ mv2
VII. Law of Conservation of Energy – the second law of thermodynamics states that energy is neither created nor destroyed. The form of energy may change, but the TOTAL amount of energy stays constant. It is because of this law that we must balance equations.
There are 5 main types listed below and the general formulas for each are given
1. combination (or synthesis) reaction A + B AB
2. decomposition AB A + B
3. single replacement A + BC AC + B
4. double replacement AB + CD AD + CB the positive ion is always written first.
5. combustion CxHy + O2 CO2 + H2O here oxygen is always a reactant and carbon dioxide and water are always products in a COMPLETE combustion reaction.
Where 2 or more simple substances (elements or compounds) combine to form ONE complex substance
Ex: 8Fe + S8 8FeS
2Sr + O2 2SrO
Mg + Br2 MgBr2
14. Li + P4 ______________
15. N2+ Al ______________________
16. Cl2+ Ca ______________
17. Na + N2 _____________________
A complex substance (compound) decomposes into 2 or more simple substances. Heat or electricity is usually required.
2NaCl 2 Na + Cl2
8MgS 8Mg + S8
Where oxygen reacts with another substance, usually a hydrocarbon, resulting in the release of energy, usually heat or light. A hydrocarbon is a compound containing carbon and hydrogen, although we will work combustion reactions with compounds containing hydrogen, carbon and oxygen sometimes. There are 2 types of combustion reactions:
Incomplete – instead of CO2 being produced, the products may be CO, CO2 and/or C. Water is also a product
Complete – carbon dioxide and water are the only products
CH4 + 202 CO2 + 2H20
Hint: Balancing combustion reactions: balance the carbons first, balance the hydrogens next, balance the oxygens last.
Examples of Combustion Reactions:
23. C3H8+ O2
24. C2H2+ 5O2
25. Ca + O2
Occurs when one element displaces another element in a compound. You must check the “Activity Series of Metals” (see below) to see if the “lone” element is active or “strong” enough to displace the element in the compound.
26. Li + KCl _____________
27. Sn + ZnCl2 ________________
28. Sn + HCl _______________
29. Ni + HOH ________________
Certain nonmetals, the halogens, also behave like this. The order of “strength” of the halogens is
30. Cl2+ NaBr
31. I2+ KBr
32. F2+ MgBr2
33. Br2+ CaCl2
Occur when the cations (positive ions) “switch” places. You do NOT need the “activity series of metals” list in these reactions. When you switch places, be sure to correctly write the formula of the new compound!!!!!
Ex: 2 NaCl + MgO MgCl2 + Na2O
2 KMn04 + Na2C2O4 2 NaMnO4 + K2C2O4
34. NaBr+ AgNO3
35. CuS04+ Al(OH)3
36. Ca3(P04)2+ ZnCr04
1. Predict the products of the double-replacement reaction and indicate the solubility of both of the products by placing the symbol "(aq)" after the soluble product and the symbol "(s)" after the insoluble product.
Use the “Solubility Rules” handout (at end of notes) to determine the solubility.
If the compound is soluble that means that it will remain as ions in the solution, if it is insoluble then the compound precipitated out of the reaction (it became the precipitate or solid).
2. If at least one INSOLUBLE product is formed (which means a precipitate will form) the reaction will occur!
3. If only SOUBLE products are formed then the reaction will NOT occur (because no precipitate is formed)! **Only exception is when the reaction occurs and a gas is produced and not a ppt, but you will learn about those in AP!!!!**
5. If the reaction occurs and one of the compounds formed is soluble then that compound is written as ions and not as a compound.
ex. BaCO3 + CuSO4 BaSO4(s) + CuCO3 (s)
ex. K3PO4 + NaOH no reaction occurred (no ppt)
ex. Na2S + Cd(NO3)2 Na+ + NO3 + CdS(s)
shows only the compounds and ions that undergo a chemical change in a double replacement reaction
Example: Na2S + Cd(NO3)2 Na+ + NO3 + CdS(s)
Step 1: Convert the chemical equation to an overall ionic equation. All reactants are shown as ions. For the products, all soluble ionic compounds are shown as dissociated ions and the precipitates are shown as solids.
Step 2: All spectator ions (ions that do not take part in a chemical reaction and are found as ions both before and after the reaction) are removed from the equation.
(Write the chemical equation for each as well as the net ionic equation.)
37. CuCO3+ NaCl
38. Na2S + Cd(NO3)2
39. Ba(NO3)2+ NaCl
Practice: In this practice section, just tell what type of reaction it is.
41. C2H4+ 02
42. Zn + AgNO3
44. Al + P
45. NaI+ MgS
46. Cl2+ NaBr
47. C6H1206+ O2
Predicting products - in this section, predict the actual products: (balance too)
48. AlCl3 + Na2CO3
49. Ni + MgSO4
50. Cl2+ K
51. C5H12+ 02
53. methane (CH4)gas is burned in the presence of oxygen
54. potassium bromide solution is mixed with chlorine gas
55. calcium metal is placed into liquid iodine