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NU-MRSEC Transparent Conducting Oxides Northwestern University DMR-0076097 Tobin J. Marks, Vinayak Dravid, Arthur J. Freeman, Carl R. Kannewurf.

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  1. NU-MRSEC Transparent Conducting OxidesNorthwestern University DMR-0076097Tobin J. Marks, Vinayak Dravid, Arthur J. Freeman, Carl R. Kannewurf Transparent conducting oxides (TCOs) are essential components of numerous flat panel display, heat management, and solar energy systems. Progress in any of these areas will require new generations of TCOs with improved properties. Nevertheless, these materials are poorly understood, and a major advance would significantly impact the aforementioned technologies. Simple, face-centered cubic CdO is an ideal model material to study the fundamental aspects of those factors governing TCO conductivity, transparency, and work function. A detailed study of doping effects was carried out by Marks, Dravid, Freeman, and Kannewurf utilizing a new series of metal-organic precursors to grow high-quality MxCd1-xO films. A series of yttriumdoped CdO (CYO) thin films were grown on amorphous glass and single-crystal MgO(100) substrates by metal-organic chemical vapor deposition (MOCVD), and phase structure, microstructure, electrical, and optical properties investigated. XRD data reveal that the asdeposited CYO thin films are phase-pure and polycrystalline, with features assignable to a cubic CdO-type structure. Epitaxial films grown on single-crystal MgO(100) exhibit biaxial, highly textured microstructures. The CYO thin films exhibit excellent optical transparency (averagetransmittance of > 80 % in the visible), and Y doping widens the optical band gap from 2.86 to 3.27 eV via a Burstein-Moss shift. Room temperature film conductivities of 8,540 S/cm and 17,800 S/cm on glass and MgO(100), respectively, are obtained at an Y-doping level of 1.2~1.3 %. Band structure calculations were employed to systematically compare the structural, electronic, and optical properties of In-, Sc-, and Y-doped CdO. The joint experimental and theoretical results reveal that dopant ionic radius and electronic structure have a significant influence on the CdO-based TCO crystal and band structure: (1) lattice parameters contract as a function of dopant ionic radius in the order Y (1.09 Å) < In (0.94 Å) < Sc (0.89 Å), with smaller ions weakening Cd-O hybrization; (2) carrier mobilities and doping efficiencies decrease in the order In > Y > Sc; (3) the dopant s state has substantial influence on the position and width of the s-based conduction band, which ultimately determines intrinsic charge transport characteristics; hybridization falls in the order In < Y < Sc. Figure. Calculated charge density distribution in the ab plane within the energy window of 0.027 eV below the Fermi level for In-, Y-, and Sc-doped CdO. Atoms within one unit cell are labeled.

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