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1. Yi Huang, Dan Li, Huanting Wang*Department of Chemical EngineeringMonash UniversityClayton, VIC 3800 Australia. huanting.wang@eng.monash.edu.au Zeolite-polymer composite membranes for desalination
2. Zeolites — Molecular sieves
3. Zeolites: potential for desalination Pore size
5. Synthesis of zeolite membranes In-situ and secondary growth
Microwave heating synthesis
Dry-gel conversion
Defects: cracks, pinholes, inter-crystal gaps
6. Ion rejection by MFI zeolite membrane
7. Thin zeolite-polymer composite membranes
8. Hand-cast and commercial membrane separation performance
9. Developing zeolite-polymer membranes Zeolite nanocrystals: crystal size, size distribution, pore size (crystal structure)
Interfacial compatibility and defects
10. Synthesis of zeolite nanocrystals Controlling zeolite nucleation and growth
Involving structure –directing agents (SDA)
Synthesis of SDA-free zeolite nanocrystals??
11. Confined-space synthesis Activated carbon as inert matrix
Polymer hydrogels
12. Carbon matrix in confined space synthesis Nanocrystal aggregates
Infiltration of zeolite gels
Crystallization outside the carbon matrix
13. Synthesis of zeolite nanocrystals in thermoreversible polymer hydrogels
16. Colloidal silica nanoparticles Commercially available
Mondisperse silica can be readily prepared by Stober’s method. (Stober, W.; Fink, A. J. Colloid Interface Sci. 1968, 26, 62-69).
17. Direct conversion?
26. Advantages of our new method controlling nanocrystal size distribution via silica size distribution
eliminating crystallization outside the mesoporous carbon matrix
producing dispersible zeolite nanocrystals (no intercrystal growth)
28. Acknowledgement PhD students:
Yi Huang
Dan Li
Funding:
CSIRO Water for a Healthy Country
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