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Graft copolymers

Macromonomers. v.dif. Graft copolymers. easier. X is usually alkene but it can also be a difunctional group for step growth polymerization. Chain growth. Radical polymerization Transfer. Reading for interest S. Rimmer, A.N. Mohd. Ramli, S. Lefèvre, Polym er, 37 , 4135 (1996).

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Graft copolymers

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  1. Macromonomers v.dif Graft copolymers easier X is usually alkene but it can also be a difunctional group for step growth polymerization

  2. Chain growth • Radical polymerization • Transfer Reading for interest S. Rimmer, A.N. Mohd. Ramli, S. Lefèvre, Polymer, 37, 4135 (1996)

  3. Living polymerization Styrene/ Cu(II) Reading for interest Y. Shen, S. Zhu, F. Zeng, R. Pelton Macromolecules 2000, 33, 5399-5404

  4. Anionic polymerization-Living polymerization mCPBA= m-chloroperbenzoic acid Reading for interest J. Rieger,K. V. Bernaerts, F. E. Du Prez, R. Jerome, C. Jerome Macromolecules 2004, 37, 9738-9745

  5. Another example N. Vazaios, N. Hadjichristidis J. Polym. Sci A 43, Issue 5, 2005, 1038-1048 For a good review of graft copolymers by anionic polymerization see “Polymers with Complex Architecture by Living Anionic Polymerization” Nikos Hadjichristidis, Marinos Pitsikalis, Stergios Pispas, and Hermis Iatrou Chem. Rev. 2001, 101, 3747-3792 Essential reading

  6. Cationic polymerization Reading for interest Kenji Yamada, Masayuki Miyazaki, Kohji Ohno, Takeshi Fukuda, and Masahiko Minoda Macromolecules 1999, 32, 290-293

  7. Reading for interest D. M. Weisberg, B.Gordon, G. Rosenberg, A. J. Snyder, A. Benesi, and James Runt Macromolecules 2000, 33, 4380-4389

  8. Synthesis of an amphiphilic polymer

  9. Ring opening polymerization Reading for interest Atsushi Nagai, Bungo Ochiai, and Takeshi Endo Macromolecules 2004, 37, 4417-4421

  10. Macromonomers for step growth polymerization Reading for interest Y. Chujo, Y. Tatsuda and Y. Yamashita. Polym. Bull. 1982, 8, 239 S. Rimmer, M.H. George, European Polymer Journal1993, 29, 205

  11. Grafting from M Initiating groups

  12. Controlled radical approaches Reading for interest Li et al Polymer International 55 , 25 - 30, (2006)

  13. Reading for interest Fumitaka Tasaka, Yuichi Ohya, and Tatsuro Ouchi Macromolecules 2001, 34, 5494-5500

  14. Essential reading M. Ratzsch, M. Arnold, E. Borsig, H. Buckar, N. Reichelt Progress in Polymer Science 2002, 27, 1195-1282

  15. Grafting to natural polymers Reading for interest Tang et al International Journal of Biological MacromoleculesVolume 43, (2008), 383-389

  16. Grafting from eg modification of starch Radical oxidation monomer + Ce (IV)

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